Cosmetic compositions capable of forming a multilayer structure after application to a keratinous material

ABSTRACT

Cosmetic compositions capable of forming a multilayer structure after application to a keratinous material are provided, as well as methods of applying such compositions to a keratinous material.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation of U.S. Non-provisional applicationSer. No. 16/086,960, filed on Sep. 20, 2018, which is a 35 U.S.C. § 371national stage patent application of International patent applicationPCT/US2017/025370, filed Mar. 31, 2017, which is a continuation-in-partof U.S. Non-provisional Application Serial Nos. 15/253,114 and15/253,071, both of which were filed Aug. 31, 2016, which arecontinuation-in-part applications of application Ser. Nos. 15/144,622,15/144,698 and 15/144,716, each of which was filed May 2, 2016, all fiveapplications claiming priority to U.S. Provisional Application Ser. No.62/316,309, filed Mar. 31, 2016. This application is also acontinuation-in-part of U.S. Non-provisional Application Serial Nos.15/445,684 and 15,445,634, both filed Feb. 28, 2017. The entire contentsof each application are hereby incorporated by reference.

FIELD OF THE INVENTION

The present invention relates to cosmetic compositions capable offorming a multilayer structure after application to a keratinousmaterial. Such compositions allow for benefits associated withmultilayer cosmetic products without having to engage in a multi-stepapplication process.

DISCUSSION OF THE BACKGROUND

Many cosmetic compositions, including pigmented cosmetics such asfoundations, lipsticks and eye shadows, have been formulated in anattempt to possess long wearing properties upon application.Unfortunately, many of these compositions do not generally possess bothgood long-wear/transfer-resistance properties as well as goodapplication properties, good comfort properties and/or good appearanceproperties (for example, shine, or matte properties).

For example, with respect to lip products, commercial productscontaining silicon resins such as MQ resins are known. Such products areknown to provide good long wear properties and/or transfer-resistance.However, such products possess poor application properties, poor feelupon application (for example, feel rough) and poor shine or glossproperties owing to the film formed by the MQ resin (for example, amatte appearance). Therefore, a second composition (topcoat) isseparately applied to such products to improve poor properties of thecompositions to make the products acceptable to consumers. Furthermore,the topcoat composition must be reapplied continually so that theproduct remains acceptable to consumers, meaning that the products areeffectively not “long-wearing” as they require constant maintenance andreapplication.

With respect to foundations, such products can provide good long wearproperties and/or transfer-resistance. However, suchlong-wearing/transfer-resistant products can possess poor applicationand/or feel upon properties application, as well as poor matteproperties.

Thus, there remains a need for improved “single step” cosmeticcompositions having improved cosmetic properties, particularly goodwear, feel, radiance, luminosity, and/or matte characteristics uponapplication.

SUMMARY OF THE INVENTION

The present invention relates to cosmetic compositions capable offorming a multilayer structure after application to a keratinousmaterial.

The present invention also relates to cosmetic compositions capable offorming a multilayer structure after application to a keratinousmaterial, wherein the compositions comprise at least two immisciblecomponents prior to application. Preferably, immiscibility of theimmiscible components results from an incompatibility between the twocomponents when the composition is at rest, incompatibility between thetwo components after application to a keratinous material, or both.

The present invention also relates to cosmetic compositions in the formof an emulsion capable of forming a multilayer structure afterapplication to a keratinous material, wherein the compositions compriseat least two immiscible components prior to application. The aqueousphase(s) of the emulsions may be present in one or more of theimmiscible components. Preferably, immiscibility of the immisciblecomponents results from an incompatibility between the two componentswhen the composition is at rest, incompatibility between the twocomponents after application to a keratinous material, or both.

The present invention also relates to anhydrous cosmetic compositionscapable of forming a multilayer structure after application to akeratinous material, wherein the compositions comprise at least twoimmiscible components prior to application. Preferably, immiscibility ofthe immiscible components results from an incompatibility between thetwo components when the composition is at rest, incompatibility betweenthe two components after application to a keratinous material, or both.

The present invention also relates to cosmetic compositions in the formof a dispersion capable of forming a multilayer structure afterapplication to a keratinous material, wherein the compositions compriseat least two immiscible components prior to application. The dispersionsmay contain water, or the dispersion may be anhydrous. Preferably,immiscibility of the immiscible components results from anincompatibility between the two components when the composition is atrest, incompatibility between the two components after application to akeratinous material, or both.

The present invention also relates to colored cosmetic compositionscapable of forming a multilayer structure after application to akeratinous material, wherein the compositions comprise at least twoimmiscible components prior to application. The compositions furthercomprise at least one coloring agent which may be present in one or moreof the immiscible components. Preferably, immiscibility of theimmiscible components results from an incompatibility between the twocomponents when the composition is at rest, incompatibility between thetwo components after application to a keratinous material, or both. Suchcolored compositions can be, for example, cosmetic compositions such aslip compositions (for example, liquid lip compositions or lipsticks)foundations, eye liners, eye shadows, mascaras, nail polishes, etc.

The present invention also relates to methods of treating, caring forand/or making up a keratinous material (for example, skin, hair,eyelashes, nails or lips) by applying compositions of the presentinvention to the keratinous material in an amount sufficient to treat,care for and/or make up the keratinous material.

The present invention also relates to methods of enhancing theappearance of a keratinous material (for example, skin, hair, eyelashes,nails or lips) by applying compositions of the present invention to thekeratinous material in an amount sufficient to enhance the appearance ofthe keratinous material.

The present invention also relates to methods of applying compositionsof the present invention to a keratinous material (for example, skin,hair, eyelashes, nails or lips) comprising mixing or blending thecomposition so that the immiscible components are temporarily miscible,and applying the composition comprising the temporarily misciblecomponents to the keratinous material. Subsequent to application to thekeratinous material, the components separate to form a multilayerstructure on the keratinous material.

The present invention also relates to kits comprising (1) at least onecontainer; (2) at least one applicator; and (3) at least one cosmeticcomposition capable of forming a multilayer structure after applicationto a keratinous material, wherein the composition comprises at least twoimmiscible components prior to application. Preferably, immiscibility ofthe immiscible components results from an incompatibility between thetwo components when the composition is at rest, incompatibility betweenthe two components after application to a keratinous material, or both.Preferably, the at least one container is configured to mix immisciblecomponents in the at least one cosmetic composition.

The present invention also relates to a cosmetic composition capable offorming a multilayer structure after application to keratinous material,preferably a composition such as a foundation, eye liners, eye shadow,mascara, or nail polish, wherein the cosmetic composition comprises atleast two immiscible Components A and B. Component A preferablycomprises about 0.01% to 60% by weight with respect to the total weightof the composition of at least one silicone- and/orhydrocarbon-containing film forming agent having at least one glasstransition temperature which is preferably lower than 60° C., preferablylower than normal human body temperature. In preferred embodiments, theat least one silicone- and/or hydrocarbon-containing film forming agentcomprises a film forming agent selected from the group consisting ofpolysaccharides, high viscosity esters, polybutenes, polyisobutenes,polyhydrogenated butenes, acrylic polymers, acrylate copolymers, vinylpyrrolidone (VP) containing homopolymers and copolymers, polyurethanes,polyolefins, silicone resins, silicone acrylate copolymers, and mixturesthereof. Component B preferably comprises about 0.01% to 90% by weightwith respect to the total weight of the composition of one or moresilicone compounds in an amount sufficient to achieve a viscosity ofabout 1,000 cSt to 22,000,000 cSt. The weight ratio of the silicone-and/or hydrocarbon-containing film forming agent(s) in Component A tosilicone compound(s) in Component B is preferably be from about 1:50 toabout 50:1, and preferably from about 1:50 to 1.5:1.

The present invention also relates to a cosmetic composition capable offorming a multilayer structure after application to keratinous material,wherein the cosmetic composition comprises at least two immiscibleComponents A and B and wherein the cosmetic composition comprises atleast one pigment and/or at least one mattifying agent. In preferredembodiments, the pigment is an inorganic pigment, preferably selectedfrom the group consisting of iron oxide, titanium oxide, ultramarineblue and combinations thereof. In preferred embodiments, the mattifyingagent is selected from the group consisting of a talc, silica, siliconeelastomer, polyamide, wax, and combinations thereof.

The present invention also relates to a cosmetic composition capable offorming a multilayer structure after application to keratinous material,wherein the cosmetic composition comprises at least two immiscibleComponents A and B and wherein Component B is self-leveling such that itimparts shine to the cosmetic composition after application to akeratinous material.

The present invention also relates to a cosmetic composition capable offorming a multilayer structure after application to keratinous material,wherein the cosmetic composition comprises at least two immiscibleComponents A and B and wherein Component A and Component B have adensity difference of 0.001-1 kg/m³. In preferred embodiments, ComponentA and Component B have a density difference of 0.01-0.6 kg/m³.

The present invention also relates to a cosmetic composition capable offorming a multilayer structure after application to keratinous material,wherein the cosmetic composition comprises at least two immiscibleComponents A and B and wherein Component A comprises at least onepolymer having a critical molecular weight of entanglement (M_(c)) suchthat M_(c)<wMw, where w=weight fraction and Mw=molecular weight of thepolymer. In preferred embodiments, Component A comprises at least onepolymer having a critical molecular weight of entanglement (M_(c)) suchthat M_(c)<wMw, where w=weight fraction and Mw=molecular weight of thepolymer. In preferred embodiments, Component B comprises at least onepolymer having a critical molecular weight of entanglement (M_(c)) suchthat M_(c)≤wMw≤10⁸ g/mol, where w=weight fraction and Mw=molecularweight of the polymer.

It is to be understood that both the foregoing general description andthe following detailed description are exemplary and explanatory only,and are not restrictive of the invention.

DETAILED DESCRIPTION OF THE INVENTION

As used herein, the expression “at least one” means one or more and thusincludes individual components as well as mixtures/combinations.

Other than in the operating examples, or where otherwise indicated, allnumbers expressing quantities of ingredients and/or reaction conditionsare to be understood as being modified in all instances by the term“about,” meaning within 10% to 15% of the indicated number.

“Film former” or “film forming agent” as used herein means a polymer orresin that leaves a film on the substrate to which it is applied.

“Polymer” as used herein means a compound which is made up of at leasttwo monomers.

“Substituted” as used herein, means comprising at least one substituent.Non-limiting examples of substituents include atoms, such as oxygenatoms and nitrogen atoms, as well as functional groups, such as hydroxylgroups, ether groups, alkoxy groups, acyloxyalky groups, oxyalkylenegroups, polyoxyalkylene groups, carboxylic acid groups, amine groups,acylamino groups, amide groups, halogen containing groups, ester groups,thiol groups, sulphonate groups, thiosulphate groups, siloxane groups,hydroxyalkyl groups, and polysiloxane groups. The substituent(s) may befurther substituted.

“Volatile”, as used herein, means having a flash point of less thanabout 100° C.

“Non-volatile”, as used herein, means having a flash point of greaterthan about 100° C.

“Anhydrous” means the compositions contain less than 1% water.Preferably, the compositions of the present invention contain less than0.5% water, and most preferably no water.

“Transfer resistance” as used herein refers to the quality exhibited bycompositions that are not readily removed by contact with anothermaterial, such as, for example, a glass, an item of clothing or theskin, for example, when eating or drinking. Transfer resistance may beevaluated by any method known in the art for evaluating such. Forexample, transfer resistance of a composition may be evaluated by a“kiss” test. The “kiss” test may involve application of the compositionto human keratin material such as hair, skin or lips followed by rubbinga material, for example, a sheet of paper, against the hair, skin orlips after expiration of a certain amount of time following application,such as 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14 or 15 minutes afterapplication. Similarly, transfer resistance of a composition may beevaluated by the amount of product transferred from a wearer to anyother substrate, such as transfer from the hair, skin or lips of anindividual to a collar when putting on clothing after the expiration ofa certain amount of time following application of the composition to thehair, skin or lips. The amount of composition transferred to thesubstrate (e.g., collar, or paper) may then be evaluated and compared.For example, a composition may be transfer resistant if a majority ofthe product is left on the wearer's hair, skin or lips. Further, theamount transferred may be compared with that transferred by othercompositions, such as commercially available compositions. In apreferred embodiment of the present invention, little or no compositionis transferred to the substrate from the hair, skin or lips.

“Adhesion” as used herein refers to the quality exhibited bycompositions that adhere to a substrate after application. Adhesion maybe evaluated by any method known in the art for evaluating such. Forexample, samples to be tested for adhesion properties can be depositedonto a surface such as a bioskin substrate or Byko-Charts Black ScrubPanels P122-10N (6.50×17.00 inches). After drying, a piece of ASTM crosshatch tape (Permacel 99/PA-28060/51596) can be placed on the sample, andremoved at a 180° angle. Then, it can be determined how much of thesample is adhered to the tape. For example, a rating scale such as ascale of 1-3 can be used to assess the degree of sample removal from thesubstrate onto the tape, in which 1 is essentially no removal, 2 is someremoval, and 3 is essentially complete removal.

The term “rub-off resistance” as used herein refers to physical abrasionsuch as rubbing the human skin with the hands or clothes or otherphysical interaction. It can also be described as the ability to holdactive ingredients on the skin or prevent the removal of activeingredients from the skin or a substrate such as Byko-Charts Black ScrubPanels P122-10N (6.50×17.00 inches) or bioskin by abrasion or otherphysical interaction.

“Gloss” in compositions as used herein refers to compositions havingwith an average gloss, measured at 60°, of greater than or equal to 35,for example 40, preferably 45, 55, 60 or 65 out of 100, including allranges and subranges therebetween such as 35-65, 40-65, etc.

The term “average gloss” denotes the gloss as it can be measured using agloss meter, for example by spreading a layer of the composition to betested, between 50 μm and 500 μm in thickness, on a Leneta contrast cardor BYK Opacity chart of reference Form 1A Penopac using an automaticspreader. The layer covers at least the white and/or black background ofthe card. The deposit is left to dry for 24 hours at a temperature ofroom temperature and then the gloss is measured at 60° on the whitebackground using a Byk Gardner gloss meter of reference microTRI-GLOSS.This measurement (of between 0 and 100) is repeated at least threetimes, and the average gloss is the average of the at least three

“Tack” as used herein refers to the quality exhibited by compositionsthat adhere to an object after application to a substrate. Tack may beevaluated by any method known in the art for evaluating such, such asusing a texture analyzer. For example, a sample can be applied to asubstrate, allowed to dry, and contacted by an object such as a½″stainless steel ball probe, after which the force associated withremoval of the object can be measured.

“Long wear” compositions as used herein, refers to compositions wherecolor remains the same or substantially the same as at the time ofapplication, as viewed by the naked eye, after an extended period oftime. Long wear properties may be evaluated by any method known in theart for evaluating such properties. For example, long wear may beevaluated by a test involving the application of a composition to theskin and evaluating the color of the composition after an extendedperiod of time. For example, the color of a composition may be evaluatedimmediately following application to skin and these characteristics maythen be re-evaluated and compared after a certain amount of time.Further, these characteristics may be evaluated with respect to othercompositions, such as commercially available compositions. Alternativelyor additionally, long wear properties may be evaluated by applying asample, allowing it to dry, and then abrading the sample to determineremoval/loss of sample.

The composition of the present invention may be in any form, eitherliquid or non-liquid (semi-solid, soft solid, solid, etc.). For example,it may be a paste, a solid, a gel, or a cream. The composition may be anemulsion, such as an oil-in-water or water-in-oil emulsion, a multipleemulsion, such as an oil-in-water-in-oil emulsion or awater-in-oil-in-water emulsion, or a solid, rigid or supple gel. Thecomposition of the invention may, for example, comprise an external orcontinuous fatty phase. The composition can also be a molded compositionor cast as a stick or a dish.

The cosmetic compositions and methods of the present invention cancomprise, consist of, or consist essentially of the essential elementsand limitations of the invention described herein, as well as anyadditional or optional ingredients, components, or limitations describedherein or otherwise useful in personal care.

Compositions Capable of Forming a Multilayer Structure

In accordance with various embodiments of the present invention,cosmetic compositions capable of forming a multilayer structure afterapplication to a keratinous material are provided. Such compositionsallow for benefits associated with multilayer cosmetic products withouthaving to engage in a multi-step application process. For example, suchcompositions can be suitable as foundations, primers, eye shadows andother skin compositions and/or can be suitable as lipsticks, lipglosses, lip balms and other lip compositions.

In accordance with one or more embodiments of the present invention, thecosmetic compositions of the present invention comprise at least twoComponents, hereinafter referred to as “Component A” and “Component B.”In one or more embodiments, both Component A and Component B comprisesilicone. Component A, for example, may comprise a silicone-containingfilm-forming agent. Component B, for example, may comprise a siliconegum. In some embodiments, Component A comprises a hydrocarbonfilm-forming agent, and Component B comprises a silicone compound.Again, Component B, for example, may comprise a silicone gum. In one ormore embodiments, Component A may comprise both a silicone-containingfilm-forming agent as well as a hydrocarbon-containing film-formingagent.

Component A is the component of the compositions of the presentinvention which forms the layer of the multilayer structure which isclosest to the keratinous material after application of the compositionto the keratinous material. This layer of the multilayer structure ishereinafter referred to as “Layer A.” In accordance with preferredembodiments, Component A/Layer A has an affinity for the surface of thekeratinous material owing to the surface energy characteristics betweenthe two.

Component B is the component of the compositions of the presentinvention which forms the layer of the multilayer structure which isfarthest away from the keratinous material after application of thecomposition to the keratinous material. This layer of the multilayerstructure is hereinafter referred to as “Layer B.” In accordance withpreferred embodiments, Component B/Layer B has an affinity for the airinterface.

In accordance with the present invention, all weight amounts and ratiosset forth herein referring to Component A and Component B refer toamounts of active material (that is, non-volatile material) in thesecomponents. Similarly, all weight amounts and ratios set forth hereinreferring to Layer A and Layer B refer to amounts of active material asLayer A and Layer B are present after evaporation of volatile solvent.

Prior to application to a keratinous material, Component A and ComponentB are immiscible in the compositions of the present invention.Preferably, immiscibility of the immiscible components results from anincompatibility between the two components when the composition is atrest, incompatibility between the two components after application to akeratinous material, or both.

In one or more embodiments, immiscibility of the immiscible componentsresults from differences such as, for example, differences in viscosity,glass transition temperature, interfacial tension, solubilityparameters, density, and/or chemical/structural incompatibility of thecomponents, and/or differences induced by temperature and/or pressure.

For example, immiscibility of the immiscible components when thecomposition is at rest can result from, for example, chemical/structuralincompatibility, differences in the interfacial tension between thecomponents such as, for example, differences in the interfacial tensionbetween the phases within mutually compatible solvent(s), differences inviscosity, differences in the glass transition temperatures of thepolymers within each phase and/or differences induced by temperatureand/or pressure.

For example, immiscibility of the immiscible components when thecomposition is being applied can result from, for example,chemical/structural incompatibility, differences in the interfacialtension between the components, differences in density of the componentsafter solvent evaporation, and/or differences induced by temperatureand/or pressure.

In one or more embodiments, immediately prior to application and/orduring application to a keratinous material, the composition of thepresent invention is mixed or blended such that Component A andComponent B are temporarily miscible upon application of the compositionof the present invention to a keratinous material.

After the composition of the present invention has been applied to akeratinous material, Component A separates from Component B. As thecomposition dries on the keratinous material to which it has beenapplied, immiscible Component A and Component B form a multilayerstructure comprising Layer A and Layer B, respectively, on thekeratinous material such as, for example:

LAYER B LAYER A KERATINOUS MATERIAL

According to one or more embodiments of the present invention, aftercompositions of the present invention have been applied to a keratinousmaterial, Component B results in Layer B which is level: that is, LayerB is planar such that it may have refractive properties to impart shineto the composition. In accordance with these embodiments, Component Bhas self-leveling properties: it results in a level Layer B afterapplication. The shine of such compositions can be enhanced, if desired,by addition of one or more shine or gloss enhancing agents having highrefractive index properties. Alternatively, such compositions can beprovided with matte properties by addition of one or more mattifyingagents.

According to preferred embodiments of the present invention, aftercompositions of the present invention have been applied to a keratinousmaterial, Component B results in Layer B which is not-level: that is,Layer B is not planar such that it imparts matte properties to thecomposition. In accordance with these embodiments, Component B does nothave self-leveling properties: it results in a non-level Layer B afterapplication. The matte properties of such compositions can be enhanced,if desired, by addition of one or more mattifying agents. Alternatively,such compositions can be provided with shine or luminosity or glossproperties by addition of one or more shine or luminosity or glossenhancing agents having high refractive index properties. Anotherbenefit of the compositions may be that, when used as a baselayer/primer, the self-leveling nature of the compositions may provide asmoothing surface, thereby reducing the appearance of skinimperfections.

In accordance with the present invention, the multilayer structurecomprises Layer A and Layer B. In certain instances, depending onfactors such as ingredient ratios, ingredient concentrations, solventevaporation characteristics, and Tg of polymers, the layers might beintermixed slightly with each other after application to a keratinousmaterial, resulting in Layer A having a larger amount of A and a smalleramount of B greater and/or Layer B having a larger amount of B and asmaller amount of A. Preferably, Layer A comprises 40% or less of LayerB, preferably 30% or less of Layer B, preferably 20% or less of Layer B,preferably 10% or less of Layer B, and preferably 5% or less of Layer B,including all ranges and subranges therebetween. Similarly, preferably,Layer B comprises 40% or less of Layer A, preferably 30% or less ofLayer A, preferably 20% or less of Layer A, preferably 10% or less ofLayer B, and preferably 5% or less of Layer A, including all ranges andsubranges therebetween.

Factors affecting the separation of Component A and Component B afterapplication to a keratinous material can include, for example, thoseproperties discussed above including but not limited to the surfaceenergy of the substrate, the density of each Component, the evaporationproperties of the solvent(s), the Tg of the film formers, and/or theviscosity of the film formers.

Although not wishing to be bound by any particular theory, it isbelieved that Component A has surface energy properties closer to thesurface energy properties of the keratinous material to which it isapplied than Component B. For example, the surface energy of skin isestimated to be 36 mN/m. Accordingly, where Component A has a surfaceenergy of about 36 mN/m, it is believed that Component A can migrate tothe skin. Component B would preferably have a lower surface energy,making it more likely that it would migrate toward the air interface.

Although not wishing to be bound by any particular theory, it isbelieved that interfacial tension of Components A and B affects phaseseparation (in particular, the rate at which the Components A and Bseparate after application). It is believed that such phase separationcan be affected by differences such as those discussed above such as,for example, differences in temperature of the Components A and B, inthe Tg of the Components A and B (the higher the Tg of a component, thelonger it will take for phase separation), in the weight fraction of thefilm formers, and/or in the pressure of the Components A and B.

Such differences will also be discussed further below.

Glass Transition Temperature (Tg)

According to preferred embodiments, Component A and/or Component Bcomprises at least one silicone- and/or hydrocarbon-containingfilm-forming agent having at least one glass transition temperaturelower than 60° C., preferably lower than 55° C., preferably lower than50° C., and preferably lower than normal human body temperature (98.6°F. or 37° C.). Preferably, Component A and/or Component B comprises atleast one silicone- and/or hydrocarbon-containing film-forming agentwhich has all of its glass transition temperature(s) below human bodytemperature (98.6° F. or 37° C.). A plasticizer can be added to adjustTg of the film forming agent(s) as is known in the art. According topreferred embodiments, Layer A and Layer B both comprise at least onefilm-forming agent having a glass transition temperature of less than37° C.

A preferred method of determining Tg is to remove all volatile solventfrom the Layer, and determine Tg by Differential Scanning calorimetry.

Density

According to preferred embodiments, Component A and Component B havedifferent density properties, and the difference is such that ComponentA and Component B are immiscible in the compositions of the presentinvention. Preferably, Component A/Layer A and Component B/Layer B havea density difference of 0.001-1 kg/m³, preferably 0.005-0.8 kg/m³, andpreferably 0.01-0.6 kg/m³, including all ranges and subrangestherebetween.

Temperature

According to preferred embodiments, Component A and Component B areaffected by temperature, and the effect is such that Component A andComponent B are immiscible in the compositions of the present inventionat temperatures below 50° C. for a predetermined amount of time as isknown in the art unlike emulsions which are considered to be stableunder such conditions.

Weight Fraction

According to preferred embodiments, Component A and/or Component Bcomprises at least one polymer such as, for example a film-forming agenthaving a critical molecular weight of entanglement (M_(c)) such that:

If present in Component A, the at least one polymer has an M_(c)<wMw,where w=weight fraction and Mw=molecular weight of the polymer; and

If present in Component B, the at least one polymer has M_(c)≤wMw≤10⁸g/mol.

Further, according to preferred embodiments, the viscosity of the atleast one polymer in Component B is greater than 350 cSt, preferablygreater than 500 cSt, preferably greater than 750 cSt, and preferablygreater than 1000 cSt, including all ranges and subranges therebetween.

Ingredients

Component A and Component B can differ in various ways based primarilyon the different functionalities associated with Layer A and Layer B.For example, where Layer A performs a transfer-resistance or adherencefunction, ingredients of Component A can be chosen to effecttransfer-resistance or adherence. Similarly, where Layer A performs acolor-enhancing function, at least one coloring agent can be added toComponent A. And, for example, where Layer B performs a gloss- orshine-enhancing function and/or and provides a better feel (for example,affords a more comfortable feeling) and/or provides a barrier layer toinhibit color transfer, ingredients of Component B can be chosen toeffect gloss, shine, comfort and/or barrier layer properties. However,it should be understood that at the interface of Layer A and Layer B,the interface of Layer A may possess properties more associated withLayer B (for example, shine) while Layer B may possess properties moreassociated with Layer A (for example, adhesion).

According to preferred embodiments, Component A comprises at least onesilicone- and/or hydrocarbon-containing film-forming agent, at least onecoloring agent, or both, and Layer A provides adhesion,transfer-resistance and/or color properties to the multilayer structure.According to such embodiments, Component B may comprise at least oneshine-enhancing agent, at least one comfort agent and/or at least onebarrier agent, and Layer B provides shine, comfort and/or barrierproperties to the multilayer structure.

According to preferred embodiments, the compositions of the presentinvention contain less than 1% wax and/or less than 1% fluorinatedcompound.

According to preferred embodiments, the compositions of the presentinvention contain less than 0.5% wax and/or less than 0.5% fluorinatedcompound.

According to preferred embodiments, the compositions of the presentinvention contain no wax and/or no fluorinated compound.

According to preferred embodiments, at least one of the same solvent(s)is used in Component A and Component B. Preferably, of total solventpresent in each Component, the majority in each Component is the same.

According to preferred embodiments, the weight ratio of Component A toComponent B is from, for example, 1:50 to 1.5:1, 1:75 to 1.5:1, 1:50 to1.5:1, 1:20 to 1.5:1, 1:50 to 50:1, 1:75 to 20:1, 1:50 to 10:1, or 1:20to 10:1, including all ranges and subranges therebetween

Examples of acceptable ingredients added to Component A and/or ComponentB are discussed below.

Film Forming Agent (Film Former)

Compositions of the present invention may comprise at least onesilicone- and/or hydrocarbon-containing film-forming agent. Silicone andhydrocarbon-containing film forming agents are known in the art, and anysilicone- and/or hydrocarbon-containing film forming agent may be used.According to preferred embodiments, at least one silicone and/orhydrocarbon-containing film forming agent having at least one glasstransition temperature lower than 60° C., preferably lower than 55° C.,preferably lower than 50° C., and preferably lower than normal humanbody temperature (98.6° F.), is included in the composition of thepresent invention. Preferably, the at least one silicone and/orhydrocarbon-containing film forming agent has all of its glasstransition temperature(s) below 60° C., preferably below than 55° C.,preferably below than 50° C., and preferably below than normal humanbody temperature (98.6° F.). The Tg property of the at least onesilicone and/or hydrocarbon-containing film forming agent can resultfrom various ways known in the art such as, for example, the Tg of thesilicone and/or hydrocarbon-containing film forming agent itself, thecombination of different film forming agents to achieve a Tg, forexample a Tg lower than normal human body temperature, or thecombination of film forming agent(s) and plasticizer(s) to achieve a Tg,for example a Tg lower than normal human body temperature.

According to preferred embodiments, the film forming agent(s) is/arepreferably present in an amount of from about 0.05% to about 90% byweight, preferably from 0.08% to 80% by weight, and preferably from 0.1%to 60% by weight of the total weight of the component in which they arefound, including all ranges and subranges therebetween.

According to preferred embodiments, the film forming agent(s) is/arepreferably present in an amount of from about 0.01%, 0.05%, 0.08%, 1%,2%, 3%, 4%, 5%, 6%, 7%, 8%, 9%, 10%, 11%, 12%, 13%, 14%, 15%, to about20%, 25%, 30%, 35%, 40%, 50%, 60%, 70%, 80% or 90% by weight of thetotal weight of the component in which they are found.

According to preferred embodiments, the film forming agent(s) is/arepreferably present in an amount of from about 0.1% to 60% by weight,preferably from 0.2% to 55% by weight, and preferably from 0.3% to 50%by weight of the total weight of the composition, including all rangesand subranges therebetween.

Hydrocarbon-containing Film Forming Agents (Film Former)

Compositions of the present invention may comprise at least onehydrocarbon-containing film-forming agent. As used herein,“hydrocarbon-containing film forming agent” refers to a film formingagent comprising at least about 2.5, 5, 10, 20, 30, 40, 50, 60, 70, 80,90, 95, or 99% hydrocarbon by weight. According to one or moreembodiments, the hydrocarbon-containing film forming agent comprisesless than about 5%, or less than about 1%, silicone or siloxane groups,and preferably contains no silicone or siloxane groups.

Hydrocarbon-containing film forming agents are known in the art, and anyhydrocarbon-containing film forming agent may be used. According topreferred embodiments, at least one hydrocarbon-containing film formingagent having at least one glass transition temperature lower than 60°C., preferably lower than 55° C., preferably lower than 50° C., andpreferably lower than normal human body temperature (98.6° F.), isincluded in the composition of the present invention. Preferably, the atleast one hydrocarbon-containing film forming agent has all of its glasstransition temperature(s) below 60° C., preferably below than 55° C.,preferably below than 50° C., and preferably below than normal humanbody temperature (98.6° F.). The Tg property of the at least onehydrocarbon-containing film forming agent can result from various waysknown in the art such as, for example, the Tg of thehydrocarbon-containing film forming agent itself, the combination ofdifferent film forming agents to achieve a Tg, for example Tg lower thannormal human body temperature, or the combination of film formingagent(s) and plasticizer(s) to achieve a Tg, for example a Tg lower thannormal human body temperature.

Examples of acceptable classes of hydrocarbon-containing film-formingagents include acrylic polymers, acrylate copolymers, vinyl pyrrolidone(VP) containing homopolymers and copolymers, polyurethanes, polyolefinsand mixtures thereof.

Acrylic Polymers

Acceptable acrylic polymer film forming agents are known in the art andinclude, but are not limited to, those disclosed in U.S. patentapplication 2004/0170586 and U.S. patent application 2011/0020263, theentire contents of which are hereby incorporated by reference.

“Acrylic polymer film formers” as used herein refers to polymers thatare film forming agents and which are based upon one or more(meth)acrylic acid (and/or corresponding (meth)acrylate) monomers orsimilar monomers. In further embodiments, the acrylic polymer filmformers do not contain any silicone or siloxane groups.

Non-limiting representative examples of such film forming agents includecopolymers containing at least one apolar monomer, at least oneolefinically unsaturated monomer, and at least one vinylicallyfunctionalized monomer.

For the apolar monomers, acrylic monomers which comprise acrylic andmethacrylic esters with alkyl groups composed of 4 to 14 C atoms,preferably 4 to 9 C atoms are preferred. Examples of monomers of thiskind are n-butyl acrylate, n-butyl methacrylate, n-pentyl acrylate,n-pentyl methacrylate, n-amyl acrylate, n-hexyl acrylate, hexylmethacrylate, n-heptyl acrylate, n-octyl acrylate, n-octyl methacrylate,n-nonyl acrylate, isobutyl acrylate, isooctyl acrylate, isooctylmethacrylate, and their branched isomers, such as, for example,2-ethylhexyl acrylate, 2-ethylhexyl methacrylate.

For olefinically unsaturated monomers, it is preferred to use monomershaving functional groups selected from hydroxyl, carboxyl, sulphonicacid groups, phosphonic acid groups, acid anhydrides, epoxides, andamines. Particularly preferred examples of olefinically unsaturatedmonomers include acrylic acid, methacrylic acid, itaconic acid, maleicacid, fumaric acid, crotonic acid, aconitic acid, dimethylacrylic acid,beta-acryloyloxypropionic acid, trichloracrylic acid, vinylacetic acid,vinylphosphonic acid, itaconic acid, maleic anhydride, hydroxyethylacrylate, hydroxypropyl acrylate, hydroxyethyl methacrylate,hydroxypropyl methacrylate, 6-hydroxyhexyl methacrylate, allyl alcohol,glycidyl acrylate, glycidyl methacrylate.

For vinylically functionalized compounds, preferred monomers includemonomers which are copolymerizable with one or both of the previouslydiscussed monomers and include, for example, methyl acrylate, ethylacrylate, propyl acrylate, methyl methacrylate, ethyl methacrylate,benzyl acrylate, benzyl methacrylate, sec-butyl acrylate, tert-butylacrylate, phenyl acrylate, phenyl methacrylate, isobornyl acrylate,isobornyl methacrylate, tert-butylphenyl acrylate, tert-butylphenylmethacrylate, dodecyl methacrylate, isodecyl acrylate, lauryl acrylate,n-undecyl acrylate, stearyl acrylate, tridecyl acrylate, behenylacrylate, cyclohexyl methacrylate, cyclopentyl methacrylate,phenoxyethyl acrylate, phenoxyethyl methacrylate, 2-butoxyethylmethacrylate, 2-butoxyethyl acrylate, 3,3,5-trimethylcyclohexylacrylate, 3,5-dimethyladamantyl acrylate, 4-cumylphenyl methacrylate,cyanoethyl acrylate, cyanoethyl methacrylate, 4-biphenyl acrylate,4-biphenyl methacrylate, 2-naphthyl acrylate, 2-naphthyl methacrylate,tetrahydrofurfuryl acrylate, diethylaminoethyl acrylate,diethylaminoethyl methacrylate, dimethylaminoethyl acrylate,dimethylaminoethyl methacrylate, 2-butoxyethyl acrylate, 2-butoxyethylmethacrylate, methyl 3-methoxyacrylate, 3-methoxybutyl acrylate,phenoxyethyl acrylate, phenoxyethyl methacrylate, 2-phenoxyethylmethacrylate, butyldiglycol methacrylate, ethylene glycol acrylate,ethylene glycol monomethylacrylate, methoxy-polyethylene glycolmethacrylate 350, methoxy-polyethylene glycol methacrylate 500,propylene glycol monomethacrylate, butoxydiethylene glycol methacrylate,ethoxytriethylene glycol methacrylate, dimethylaminopropylacrylamide,dimethylaminopropylmethacrylamide, N-(1-methylundecyl)acrylamide,N-(n-butoxymethyl)acrylamide, N-(butoxymethyl)methacrylamide,N-(ethoxymethyl)acrylamide, N-(n-octadecyl)acrylamide, and alsoN,N-dialkyl-substituted amides, such as, for example,N,N-dimethylacrylamide, N,N-dimethylmethacrylamide, N-benzylacrylamides,N-isopropylacrylamide, N-tert-butylacrylamide, N-tert-octylacrylamide,N-methylolacrylamide, N-methylolmethacrylamide, acrylonitrile,methacrylonitrile, vinyl ethers, such as vinyl methyl ether, ethyl vinylether, vinyl isobutyl ether, vinyl esters, such as vinyl acetate, vinylchloride, vinyl halides, vinylidene chloride, vinylidene halide,vinylpyridine, 4-vinylpyridine, N-vinylphthalimide, N-vinyllactam,N-vinylpyrrolidone, styrene, a- and p-methylstyrene, a-butylstyrene,4-n-butylstyrene, 4-n-decylstyrene, 3,4-dimethoxystyrene, macromonomerssuch as 2-polystyrene-ethyl methacrylate (molecular weight Mw of 4000 to13 000 g/mol), poly(methyl methacrylate)ethyl methacrylate (Mw of 2000to 8000 g/mol).

An example of an acrylic polymer is a copolymer of acrylic acid,isobutyl acrylate and isobornyl acetate such as that sold under thenames Pseudoblock (Chimex) and Synamer-3. In both of these commercialproducts, the copolymer is present with a solvent in a 1:1 ratio (50%solid). Another preferred film former is Poly(isobornyl methacrylate-8co-isobornyl acrylate-co-isobutyl acrylate-co-acrylic acid) at 50% ofactive material in 50% of octyldodecyl neopentanoate, (Mexomere PAZ fromChimex).

Vinylpyrrolidone Polymers

Acceptable vinylpyrrolidone polymers include vinylpyrrolidonehomopolymers and vinylpyrrolidone copolymers. Such homopolymers andcopolymers can be crosslinked or non-crosslinked. For example,particularly suitable polymers are vinylpyrrolidone homopolymers such asthe Polymer ACP-10. Further examples include copolymers produced fromalpha-olefin and vinylpyrrolidone in which the copolymer containsvinylpyrrolidone and an alkyl component, preferably containing at leastone C4-C30 moiety (substituted or unsubstituted) in a concentrationpreferably from 10 to 80 percent of the copolymer. Suitable examples ofcommercially available copolymers include those available from Ashlandunder the Ganex name such as, for example, VP/eicosene (GANEX V-220) andVP/tricontanyl copolymer (GANEX WP660).

Silicone-Containing Film Forming Agent (Film Former)

Compositions of the present invention may comprise at least onesilicone-containing film forming agent. As used herein,“silicone-containing film forming agent” refers to a film forming agentthat contains silicone. In one or more embodiments, “silicone-containingfilm forming agent” includes polymers that contain at least about 2.5%,5%, 10%, 20%, 30%, 40%, 50%, 60%, 70%, 80%, 90%, 95%, or 99% silicone byweight. Silicone-containing film forming agents are known in the art,and any silicone-containing film forming agent may be used. According topreferred embodiments, at least one silicone-containing film formingagent having at least one glass transition temperature lower than 60°C., preferably lower than 55° C., preferably lower than 50° C., andpreferably lower than normal human body temperature (98.6° F.), isincluded in the composition of the present invention. Preferably, the atleast one silicone-containing film forming agent has all of its glasstransition temperature(s) below 60° C., preferably below than 55° C.,preferably below than 50° C., and preferably below than normal humanbody temperature (98.6° F.). The Tg property of the at least onesilicone-containing film forming agent can result from various waysknown in the art such as, for example, the Tg of the silicone-containingfilm forming agent itself, the combination of different film formingagents to achieve a Tg, for example a Tg lower than normal human bodytemperature, or the combination of film forming agent(s) andplasticizer(s) to achieve a Tg, for example a Tg lower than normal humanbody temperature.

Examples of acceptable classes of silicone-containing film formingagents include silicone resins, silicone acrylate copolymers, andmixtures thereof.

Silicone Resin

As used herein, the term “resin” means a crosslinked or non-crosslinkedthree-dimensional structure. Silicone resin nomenclature is known in theart as “MDTQ” nomenclature, whereby a silicone resin is describedaccording to the various monomeric siloxane units which make up thepolymer.

Each letter of “MDTQ” denotes a different type of unit. The letter Mdenotes the monofunctional unit (CH₃)₃SiO_(1/2). This unit is consideredto be monofunctional because the silicone atom only shares on oxygenwhen the unit is part of a polymer. The “M” unit can be represented bythe following structure:

At least one of the methyl groups of the M unit may be replaced byanother group, e.g., to give a unit with formula [R(CH₃)₂]SiO_(1/2), asrepresented in the following structure:

wherein R is chosen from groups other than methyl groups. Non-limitingexamples of such groups other than methyl groups include alkyl groupsother than methyl groups, alkene groups, alkyne groups, hydroxyl groups,thiol groups, ester groups, acid groups, ether groups, wherein thegroups other than methyl groups may be further substituted.

The symbol D denotes the difunctional unit (CH₃)₂SiO_(2/2) wherein twooxygen atoms bonded to the silicone atom are used for binding to therest of the polymer. The “D” unit, which is the major building block ofdimethicone oils, can be represented as:

At least one of the methyl groups of the D unit may be replaced byanother group, e.g., to give a unit with formula [R(CH₃)₂]SiO_(1/2).

The symbol T denotes the trifunctional unit, (CH₃)SiO_(3/2) and can berepresented as:

At least one of the methyl groups of the T unit may be replaced byanother group, e.g., to give a unit with formula [R(CH₃)₂]SiO_(1/2).

Finally, the letter Q means a tetrafunctional unit SiO_(4/2) in whichthe silicon atom is bonded to four hydrogen atoms, which are themselvesbonded to the rest of the polymer.

Thus, a vast number of different silicone polymers can be manufactured.Further, it would be clear to one skilled in the art that the propertiesof each of the potential silicone polymers will vary depending on thetype(s) of monomer(s), the type(s) of substitution(s), the size of thepolymeric chain, the degree of cross linking, and size of any sidechain(s).

Non-limiting examples of silicone polymers include siloxysilicates andsilsesquioxanes.

A non-limiting example of a siloxysilicate is trimethylsiloxysilicate,which may be represented by the following formula:

[(CH₃)₃XSiXO]_(x)X(SiO_(4/2))_(y)

(i.e, MQ units) wherein x and y may, for example, range from 50 to 80.Silsesquioxanes, on the other hand, may be represented by the followingformula:

(CH₃SiO_(3/2))_(.x)

(i.e., T Units) wherein x may, for example, have a value of up toseveral thousand.

Resin MQ, which is available from Wacker, General Electric and DowCorning, is an example of an acceptable commercially-availablesiloxysilicate. For example, trimethylsiloxysilicate (TMS) iscommercially available from General Electric under the tradename SR1000and from Wacker under the tradename TMS 803. TMS is also commerciallyavailable from Dow Chemical in a solvent, such as for example,cyclomethicone. However, according to the present invention, TMS may beused in the form of 100% active material, that is, not in a solvent.

Suitable silicon resins comprising at least one T unit in accordancewith the present invention are disclosed, for example, in U.S. patentapplication publication numbers 2007/0166271, 2011/0038820,2011/0002869, and 2009/0214458, the entire contents of which are herebyincorporated by reference in their entirety.

Where the silicone resin contains at least one T unit, it may thus be,for example, a T, MT, MTQ or MDTQ resin.

According to preferred embodiments, the unit composition of the siliconeresin can be at least 50% T units, or at least 70% T units, or at least80% T units, or at least 90% T units.

In the M, D and T units listed as examples above, at least one of themethyl groups may be substituted. According to preferred embodiments,the at least one silicone resin comprising at least one trifunctionalunit of formula (R)SiO_(3/2) is chosen from the silsesquioxanes offormula: ((R′)SiO_(3/2))_(x), in which x ranges from 100 to 500 and R′is chosen, independently by trifunctional unit, from a hydrocarbon-basedgroup containing from 1 to 10 carbon atoms or a hydroxyl group, on thecondition that at least one R′ is a hydrocarbon-based group. Accordingto preferred embodiments, the hydrocarbon-based group containing from 1to 10 carbon atoms is a methyl group. According to preferredembodiments, the at least one silicone resin comprising at least onetrifunctional unit of formula (R)SiO_(3/2) is chosen from thesilsesquioxanes of the formula: ((R′)SiO_(3/2))_(x), in which x rangesfrom 100 to 500 and R′ is chosen, independently by unit, from CH₃, ahydrocarbon-based group containing from 2 to 10 carbon atoms, or ahydroxyl group, on the condition that at least one R′ is ahydrocarbon-based group.

According to preferred embodiments, the T resins may contain M, D and Qunits such that at least 80 mol % or at least 90 mol %, relative to thetotal amount of silicones, are T units. The T resins may also containhydroxyl and/or alkoxy groups. The T resins may have a total weight ofhydroxyl functions ranging from 2% to 10% and a total weight of alkoxyfunctions that may be up to 20%; in some embodiments, the total weightof hydroxyl functions ranges from 4% to 8% and the total weight ofalkoxy functions may be up to 10%.

The silicone resin may be chosen from silsesquioxanes that arerepresented by the following formula: ((CH₃)SiO_(3/2))_(x), in which xmay be up to several thousand and the CH₃ group may be replaced with anR group, as described previously in the definition of the T units. Thenumber x of T units of the silsesquioxane may be less than or equal to500, or it may range from 50 to 500, including all ranges and subrangestherebetween. The molecular weight of the silicone resin may range fromabout 500, 1000, 5,000, 10,000, 15,000 or 20,000 g/molto about 30,000,35,000, 40,000, 45,000, 50,000, 75,000 or 100,000 g/mol, including allranges and subranges therebetween.

As suitable examples of these silicone resins containing at least one Tunit, mention may be made of:

polysilsesquioxanes of formula ((R)SiO_(3/2))_(x) (T units) in which xis greater than 100, in which the R groups may independently be methylor other substituents as defined above;

polymethylsilsesquioxanes, which are polysilsesquioxanes in which R is amethyl group. Such polymethylsilsesquioxanes are described, for example,in U.S. Pat. No. 5,246,694, the entire contents of which is herebyincorporated by reference in its entirety;

polypropylsilsesquioxanes, in which R is a propyl group. These compoundsand their synthesis are described, for example, in patent application WO2005/075567, the entire contents of which is hereby incorporated byreference in its entirety; and

polyphenylsilsesquioxanes, in which R is a phenyl group. These compoundsand their synthesis are described, for example, in patent application US2004/0180011, the entire contents of which is hereby incorporated byreference in its entirety.

Examples of commercially available polymethylsilsesquioxane resins thatmay be mentioned include those sold:

by the company Wacker under the reference Resin MK such as Belsil PMSMK: polymer comprising CH₃SiO_(3/2) repeating units (T units), which mayalso comprise up to 1% by weight of (CH₃)₂SiO_(2/2) units (D units) andhaving an average molecular weight of about 10 000 g/mol. It is thoughtthat the polymer is in a “cage” and “ladder” configuration asrepresented in the FIGURES below. The average molecular weight of theunits in “cage” configuration has been calculated as 536 g/mol. Themajority of the polymer is in the “ladder” configuration with ethoxygroups at the ends. These ethoxy groups represent 4.5% by mass of thepolymer. As these end groups can react with water, a small and variableamount of SiOH groups may also be present; and

by the company Shin-Etsu under the references KR-220L, which arecomposed of T units of formula CH₃SiO_(3/2) and have Si—OH (silanol) endgroups, under the reference KR-242A, which comprise 98% of T units and2% of dimethyl D units and have Si—OH end groups or alternatively underthe reference KR-251 comprising 88% of T units and 12% of dimethyl Dunits and have Si—OH end groups.

Examples of commercially available polypropylsilsesquioxane resins thatmay be mentioned include those sold:

by the company Dow Corning under the reference Dow Corning 670 Fluid or680 Fluid. Typically such commercially available products arepolypropylsilsesquioxane diluted in volatile oil such as volatilehydrocarbon oil or volatile silicone oil such as D5. Dow Corning 670 and680 Fluids have a general formula of R_(n)SiO_((4-n)/2) wherein R isindependently chosen from a hydrogen atom and a monovalent hydrocarbongroup comprising 3 carbon atoms, wherein more than 80 mole % of R arepropyl groups, n is a value from 1.0 to 1.4, more than 60 mole % of thecopolymer comprises RSiO_(3/2) units, and having a hydroxyl or alkoxycontent from 0.2 to 10% by weight, for example between 1 and 4% byweight, preferably between 5 and 10% by weight, and more preferablybetween 6 and 8% by weight. Preferably, the polypropylsilsesquioxaneresin has a molecular weight from about 5,000, 7,000, 10,000, 15,000,20,000, 25,000 to about 30,000, 50,000, 75,000, 100,000 g/mol and a Tgof less than about 37° C., from about −100, −50, −37, or −20 to about37° C.

Examples of commercially available polyphenylsilsesquioxane resins thatmay be mentioned include those sold:

by the company Dow Corning under the reference Dow Corning 217 FlakeResin, which is a polyphenylsilsesquioxane with silanol end groups; and

by the company Wacker under the reference Belsil SPR 45 VP.

Silicone Acrylate Copolymer

Suitable silicone acrylate copolymers include polymers comprising asiloxane group and a hydrocarbon group. In some embodiments, suchsilicone acrylate copolymers comprise at least about 10%, 20%, 30%, 40%,50%, 60%, 70%, 80%, or 90% silicone by weight. For example, suitablepolymers include polymers comprising a hydrocarbon backbone such as, forexample, a backbone chosen from vinyl polymers, methacrylic polymers,and/or acrylic polymers and at least one chain chosen from pendantsiloxane groups, and polymers comprising a backbone of siloxane groupsand at least one pendant hydrocarbon chain such as, for example, apendant vinyl, methacrylic and/or acrylic groups.

The at least one silicone acrylate copolymer can be chosen fromsilicone/(meth)acrylate copolymers, such as those as described in U.S.Pat. Nos. 5,061,481, 5,219,560, and 5,262,087, and U.S. patentapplication 2012/0301415, the entire contents of all of which are herebyincorporated by reference.

The at least one silicone acrylate copolymer may be selected frompolymers derived from non-polar silicone copolymers comprising repeatingunits of at least one polar (meth)acrylate unit and vinyl copolymersgrafted with at least one non-polar silicone chain. Non-limitingexamples of such copolymers are acrylates/dimethicone copolymers such asthose commercially available from Shin-Etsu, for example, the productssold under the tradenames KP-545 (cyclopentasiloxane (and)acrylates/dimethicone copolymer), KP-543 (butyl acetate (and)acrylates/dimethicone copolymer), KP-549 (methyl trimethicone (and)acrylates/dimethicone copolymer), KP-550 (INCI name: isododecane (and)acrylate/dimethicone copolymer), KP-561 (acrylates/stearylacrylate/dimethicone acrylates copolymer), KP-562 (acrylates/behenylacrylate/dimethicone acrylates copolymer), and mixtures thereof.Additional examples include the acrylate/dimethicone copolymers sold byDow Corning under the tradenames FA 4001 CM SILICONE ACRYLATE(cyclopentasiloxane (and) acrylates/polytrimethylsiloxymethacrylatecopolymer) and FA 4002 ID SILICONE ACRYLATE (isododecane (and)acrylates/polytrimethylsiloxymethacrylate Copolymer), and mixturesthereof.

Further non-limiting examples of such polymers and their synthesis aredisclosed, for example, in U.S. Pat. Nos. 4,972,037, 5,061,481,5,209,924, 5,849,275, and 6,033,650, and PCT applications WO 93/23446,WO 95/06078 and WO 01/32737, the disclosures of all of which are herebyincorporated by reference. These polymers may be sourced from variouscompanies. One such company is Minnesota Mining and ManufacturingCompany which offers these types of polymers under the tradenames“Silicone Plus” polymers (for example, poly(isobutylmethacrylate-co-methyl FOSEA)-g-poly(dimethylsiloxane), sold under thetradename SA 70-5 IBMMF).

Other non-limiting examples of useful silicone acrylate copolymersinclude silicone/acrylate graft terpolymers, for example, the copolymersdescribed in PCT application WO 01/32727, the disclosure of which ishereby incorporated by reference.

Other useful polymers include those described in U.S. Pat. No.5,468,477, the disclosure of which is hereby incorporated by reference.A non-limiting example of these polymers ispoly(dimethylsiloxane)-g-poly(isobutyl methacrylate), which iscommercially available from 3M Company under the tradename VS 70 IBM.

Suitable silicone acrylate copolymers include silicone/(meth)acrylatecopolymers, such as those as described in U.S. Pat. Nos. 5,061,481,5,219,560, and 5,262,087, the disclosures of which are herebyincorporated by reference. Still further non-limiting examples ofsilicone film formers are non-polar silicone copolymers comprisingrepeating units of at least one polar (meth)acrylate unit and vinylcopolymers grafted with at least one non-polar silicone chain.Non-limiting examples of such copolymers are acrylates/dimethiconecopolymers such as those commercially available from Shin-Etsu, forexample, the product sold under the tradename KP-545, or

Other non-limiting examples of silicone film formers suitable for use inthe present invention are silicone esters comprising units of formulae(A) and (B), disclosed in U.S. Pat. Nos. 6,045,782, 5,334,737, and4,725,658, the disclosures of which are hereby incorporated byreference:

R_(a)R^(E) _(b)SiO_([4-(a+b)/2])  (A); and

R′_(x)R^(E) _(y)SiO_(1/2)  (B)

wherein

R and R′, which may be identical or different, are each chosen fromoptionally substituted hydrocarbon groups;

a and b, which may be identical or different, are each a number rangingfrom 0 to 3, with the proviso that the sum of a and b is a numberranging from 1 to 3,

x and y, which may be identical or different, are each a number rangingfrom 0 to 3, with the proviso that the sum of x and y is a numberranging from 1 to 3;

R^(E), which may be identical or different, are each chosen from groupscomprising at least one carboxylic ester.

According to preferred embodiments, R^(E) groups are chosen from groupscomprising at least one ester group formed from the reaction of at leastone acid and at least one alcohol. According to preferred embodiments,the at least one acid comprises at least two carbon atoms. According topreferred embodiments, the at least one alcohol comprises at least tencarbon atoms. Non-limiting examples of the at least one acid includebranched acids such as isostearic acid, and linear acids such as behenicacid. Non-limiting examples of the at least one alcohol includemonohydric alcohols and polyhydric alcohols, such as n-propanol andbranched etheralkanols such as (3,3,3-trimethylolpropoxy)propane.

Further non-limiting examples of the at least one silicone acrylatecopolymer film former include liquid siloxy silicates and siliconeesters such as those disclosed in U.S. Pat. No. 5,334,737, thedisclosure of which is hereby incorporated by reference, such asdiisostearoyl trimethylolpropane siloxysilicate and dilauroyltrimethylolpropane siloxy silicate, which are commercially availablefrom General Electric under the tradenames SF 1318 and SF 1312,respectively.

According to one or more embodiments of the present invention, ComponentA comprises at least one silicone acrylate and at least one siliconeresin. Preferably, the at least one silicone resin is apolypropylsilsesquioxane resin.

Silicone Compounds

In one or more embodiments, compositions of the present inventioncomprise at least one silicone compound. Preferably, Component Bcomprises one or more silicone compounds which is not a film-formingagent. Also preferably, the at least one silicone compound has a surfaceenergy lower than that of the film forming agent(s) in anothercomponent. So, for example, where Component B contains at least onesilicone compound which is not a film-forming agent, the siliconecompound preferably has a surface energy which is lower than that offilm-forming agent(s) in Component A.

The silicone compound may be, for example, polymeric, comprising asilicon bonded to a minimum of one oxygen, and in even furtherembodiments, two oxygens. In some embodiments, the silicon is bonded toa hydrocarbon (e.g., C1-22 linear, branched, and/or aryl) such asmethyl, ethyl, propyl, and phenyl. In one or more embodiments, thesilicone compound comprises a polydimethylsiloxane (PDMS). In someembodiments, the silicone compound itself may be linear, branched ordendritic. In further embodiments, the silicone compound is linear orsubstantially linear. In one or more embodiments, the silicone compoundcomprises a chain termination selected from the group consisting ofhydrocarbon, alcohol, ester, acid, ketone, amine, amide, epoxy,vinylogous (e.g. alkene or alkyne group), halogen, hydride, and thelike. For example, in embodiments where the silicone compound comprisespolydimethylsiloxane, the compound may be chain end terminated with an—OH or a methyl group.

In one or more embodiments, the term “silicone compound” includes, butis not limited to, silicone gums, silicone fluids, and silicone wax. Ifpresent, the silicone compound may impart properties on the composition(e.g., enhance shine or matte quality). In one or more embodiments, thesilicone compounds are present in an amount sufficient to achieve aviscosity of greater than about 1,000 cSt and/or less than about22,000,000 cSt. In some embodiments, the viscosity ranges from about1,000, 5,000, 10,000, 20,000, 30,000, 40,000, 50,000 or 60,000 cSt toabout 100,000, 200,000, 300,000, 400,000, 500,000, 600,000, 700,000,800,000, 900,000, 1,000,000, 5,000,000, 10,000,000 or 22,000,000 cSt,including all ranges and subranges therebetween.

Shine/Luminosity Enhancing Agents

According to preferred embodiments of the present invention, at leastone shine enhancing agent can be added to Component A, Component B, orboth. Preferably, the shine enhancing agent is selected from the groupconsisting of agents which facilitate self-leveling of a layer, agentswhich have a high refractive index, and mixtures thereof. As describedbelow, such shine enhancing agents may be silicone compounds discussedabove.

In the case of compositions for skin, in particular foundationcompositions, such shine enhancing agents may impart a luminous and/ordewy effect to compositions described herein. For example, one trend forfoundation a dewy/radiant foundation (particularly long-lastingradiance), rather than a fully matte appearance. This is usuallyachieved through the addition of oils or pearls to the formula, but suchformulas may not be long-lasting. The compositions described herein mayresult in both a dewy/radiant appearance that is also long-lasting.

Suitable shine enhancing agents include those compounds having arefractive index ranging from about 1.45 to about 1.60, and a weightaverage molecular weight of preferably less than 15,000, preferably lessthan 10,000, and preferably less than 2,000. Examples of such agentsinclude, but are not limited to, phenylated silicones such as thosecommercialized under the trade name “ABIL AV 8853” by Goldschmidt, thosecommercialized under the trade names “DC 554”, “DC 555”, “DC 556” and“SF 558” by Dow Corning, and those commercialized under the trade name“SILBIONE 70633 V 30” by Rhone-Poulenc.

Additional examples of suitable phenylated silicones include, but arenot limited to, those commercialized by Wacker Silicones such as BELSILPDM 20, a phenylated silicone with a viscosity at 25° C. ofapproximately 20 cSt; BELSIL PDM 200, a phenylated silicone with aviscosity at 25° C. of approximately 200 cSt; BELSIL PDM 1000, aphenylated silicone with a viscosity at 25° C. of approximately 1000cSt.

Additional examples of suitable shine enhancing agents include, but arenot limited to, polycyclopentadiene, poly(propylene glycol) dibenzoate(nD=1.5345), aminopropyl phenyl trimethicone (nD=1.49-1.51),pentaerythrityl tetraoleate commercially available as PURESYN 4E68(nD=1.473) from ExxonMobil, and PPG-3 benzyl ether myristatecommercially available as CRODAMOL STS (nD=1.4696) from Croda Inc.

Particularly preferred shine enhancing agents are the phenylatedsilicones such as phenyl trimethicone, and trimethyl pentaphenyltrisiloxane, and esters such as pentaerythrityl tetraoleate, and PPG-3benzyl ether myristate.

Suitable shine enhancing agents include those which provideself-leveling properties to the compositions of the present invention.Suitable examples of such compositions include, but are not limited to,the silicone gums discussed below.

The silicone gum can correspond to the formula:

in which:

R₇, R₈, R₁₁ and R₁₂ are identical or different, and each is chosen fromalkyl radicals comprising from 1 to 6 carbon atoms,

R₉ and R₁₀ are identical or different, and each is chosen from alkylradicals comprising from 1 to 6 carbon atoms and aryl radicals,

X is chosen from alkyl radicals comprising from 1 to 6 carbon atoms, ahydroxyl radical and a vinyl radical,

n and p are chosen so as to give the silicone gum a viscosity of from350 cSt to 50,000,000 cSt, preferably from 500 cSt to 40,000,000 cSt,preferably from 750 cSt to 30,000,000 cSt, preferably from 850 cSt to20,000,000 cSt, preferably from 950 cSt to 18,000,000 cSt and preferablyfrom 1000 cSt to 10,000,000 cSt, including all ranges and subrangestherebetween. A particularly preferred range is from 20,000 cSt to800,000 cSt, with 25,000 cSt to 750,000 cSt being most preferred.

In general, n and p can each take values ranging from 0 to 10,000, suchas from 0 to 5,000.

Among the silicone gums which can be used according to the invention,mention may be made of those for which:

the substituents R₇ to R₁₂ and X represent a methyl group, p=0 and n=2700, such as the product sold or made under the name SE30 by the companyGeneral Electric,

the substituents R₇ to R₁₂ and X represent a methyl group, p=0 and n=2300, such as the product sold or made under the name AK 500 000 by thecompany Wacker,

the substituents R₇ to R₁₂ represent a methyl group, the substituent Xrepresents a hydroxyl group, p=0 and n=2 700, as a 13% solution incyclopentasiloxane, such as the product sold or made under the nameQ2-1401 by the company Dow Corning,

the substituents R₇ to R₁₂ represent a methyl group, the substituent Xrepresents a hydroxyl group, p=0 and n=2 700, as a 13% solution inpolydimethylsiloxane, such as the product sold or made under the nameQ2-1403 by the company Dow Corning, and

the substituents R₇, R₈, R₁₁, R₁₂ and X represent a methyl group and thesubstituents R₉ and R₁₀ represent an aryl group, such that the molecularweight of the gum is about 600 000, for instance the product sold ormade under the name 761 by the company Rhône-Poulenc (Rhodia Chimie).

In preferred embodiments, the silicone gum correspond to the followingformula:

In this formula the terminal Si's can also be other than methyl and maybe represented with substitutions on the repeating Si such that the Rgroup is an alkyl of 1 to 6 carbon atoms, which may be linear, branchedand/or functionalized selected from methyl, ethyl, propyl, isopropyl,butyl, isobutyl, t-butyl, amyl, hexyl, vinyl, allyl, cycohexyl, phenyl,and mixtures thereof. The silicone gums employed in the presentinvention may be terminated by triorganosilyl groups of the formula R′₃where R′ is a radical of monovalent hydrocarbons containing from 1 to 6carbon atoms, hydroxyl groups, alkoxyl groups and mixtures thereof.

According to preferred embodiments, Component B/Layer B comprises atleast one shine (gloss) enhancing agent.

According to preferred embodiments, Component B/Layer B has aself-leveling property which results in a flatter interface betweenLayer A and Layer B and/or between Layer B and air, and this flatterinterface results in light diffraction, refraction and/or reflectionproperties for Layer B which enhances the shine of the composition.

According to preferred embodiments of the present invention, at leasttwo silicone compounds such as silicone fluids (for example, phenylatedsilicones described above) and/or silicone gums are present in thecompositions of the present invention.

According to preferred embodiments, if present, agent(s) whichfacilitate self-leveling of a layer such as silicone gum(s) is/arepreferably present in an amount of from about 0.01% to about 90% byweight, preferably from 1% to 85% by weight, and preferably from 5% to80% by weight of the total weight of the composition, including allranges and subranges therebetween.

According to preferred embodiments, if present, agent(s) which have ahigh refractive index such as phenylated silicone oil(s) is/arepreferably present in an amount of from about 0.05% to about 90% byweight, preferably from 0.1% to 75% by weight, and preferably from 1% to50% by weight of the total weight of the composition, including allranges and subranges therebetween.

According to preferred embodiments of the present invention, at leasttwo silicone compounds such as silicone fluids (for example, phenylatedsilicones described above) and/or silicone gums are present in thecompositions of the present invention.

According to preferred embodiments, the shine enhancing (s) is/arepreferably present in an amount of from about 0.05% to about 90% byweight, preferably from 0.1% to 50% by weight, and preferably from 1% to35% by weight of the total weight of the composition, including allranges and subranges therebetween.

Matte Enhancing Agents (Mattifying Agent)

According to preferred embodiments of the present invention, at leastone matte enhancing agent can be added to Component A, Component B, orboth. With respect to Component B, the at least one matte enhancingagent can be added regardless of whether Component B is notself-leveling and/or Layer B has refractive properties to impart matteproperties to the composition as described above.

Suitable matte enhancing agents include, but are not limited to,mattifying fillers such as, for example, talc, silica, siliconeelastomers, and polyamides, and waxes such as, for example, beeswax andcopernicia cerifera (carnauba) wax.

According to preferred embodiments, the matte enhancing agent(s) is/arepreferably present in an amount of from about 0.05% to about 90% byweight, preferably from 0.1% to 50% by weight, and preferably from 1% to35% by weight of the total weight of the composition, including allranges and subranges therebetween.

Aqueous Phase

The compositions of the present invention may also optionally containwater. If present, water may be present in amounts ranging from about1%, 2%, 3%, 4%, 5%, 10%, 15%, 20%, 25%, 30%, 40%, 50%, 60%, 70%, or 80%to about 40%, 50%, 60%, 70%, 80%, 85% or 90% by weight with respect tothe total weight of the composition. In some embodiments, thecomposition does not comprise an emulsifier. Thus, water that is presentin the composition may create a separate phase from those of Component Aand B. In such embodiments, the composition is triphasic. In some otherembodiments, the water may be present in one of the phases of ComponentA or B, even without the presence of an emulsifier.

Certain water-soluble agents may be present in the aqueous phase. Forexample, the composition may comprise in the aqueous phase latexes andpolymers which are water soluble or water dispersible.

Soft Focus Agents

According to one or more embodiments, the compositions described hereincomprise a soft focus agent. As used herein, the term “soft focus” meansthat the visual appearance of the skin is more homogenous and matte,leading to the blurring or hiding of skin imperfections.

In some embodiments, the at least soft focus agent may be chosen fromhydrophobic silica aerogel particles. Silica aerogels are porousmaterials obtained by replacing (by drying) the liquid component of asilica gel with air.

Hydrophobic silica aerogel particles useful according to embodiments ofthe disclosure include silylated silica (INCI name: silica silylate)aerogel particles. The preparation of hydrophobic silica aerogelparticles that have been surface-modified by silylation is describedmore fully in U.S. Pat. No. 7,470,725, incorporated by reference herein.In various embodiments, aerogel particles of hydrophobic silicasurface-modified with trimethylsilyl groups may be chosen. For example,the aerogel sold under the name VM-2260® by the company Dow Corning, theparticles of which have an average size of about 1000 microns and aspecific surface area per unit of mass ranging from 600 to 800 m²/g, orthe aerogel sold under the name VM-2270®, also by the company DowCorning, the particles of which have an average size ranging from 5 to15 microns and a specific surface area per unit of mass ranging from 600to 800 m²/g, may be chosen. In other embodiments, the aerogels sold bythe company Cabot under the names Aerogel TLD 201®, Aerogel OGD 201®,and Aerogel TLD 203®, CAB-O-SIL TS-530, CAB-O-SIL TS-610, CAB-O-SILTS-720, Enova Aerogel MT 1 100®, and Enova Aerogel MT 1200®, may bechosen.

Other soft-focus effect agents can be found in WO/2016100690, the entirecontents of which are herein incorporated by reference.

According to preferred embodiments, if present, the soft focus agent(s)is/are preferably present in an amount of from about 0.05% to about 20%by weight, preferably from 0.1% to 15% by weight, and preferably from 1%to 10% by weight of the total weight of the composition, including allranges and subranges therebetween

Coloring Agents

According to one or more embodiments of the present invention,compositions further comprising at least one coloring agent areprovided. Preferably, such colored compositions can be cosmeticcompositions such as, for example, foundations or eye shadows. Accordingto such embodiments, the at least one coloring agent may be chosen frompigments, dyes, nacreous pigments, and pearling agents.

The pigments, which may be used according to the present invention, maybe chosen from white, colored, inorganic, organic, polymeric,nonpolymeric, coated and uncoated pigments. Representative examples ofmineral pigments include titanium dioxide, optionally surface-treated,zirconium oxide, zinc oxide, cerium oxide, iron oxides, chromium oxides,manganese violet, ultramarine blue, chromium hydrate, and ferric blue.Representative examples of organic pigments include carbon black,pigments of D & C type, and lakes based on cochineal carmine, barium,strontium, calcium, and aluminum.

Representative examples of inorganic pigments useful in the presentinvention include those selected from the group consisting of rutile oranatase titanium dioxide, coded in the Color Index under the referenceCI 77,891; black, yellow, red and brown iron oxides, coded underreferences CI 77,499, 77, 492 and, 77,491; manganese violet (CI 77,742);ultramarine blue (CI 77,007); chromium oxide (CI 77,288); chromiumhydrate (CI 77,289); and ferric blue (CI 77,510) and mixtures thereof.

Representative examples of organic pigments and lakes useful in thepresent invention include, but are not limited to, D&C Red No. 19 (CI45,170), D&C Red No. 9 (CI 15,585), D&C Red No. 21 (CI 45,380), D&COrange No. 4 (CI 15,510), D&C Orange No. 5 (CI 45,370), D&C Red No. 27(CI 45,410), D&C Red No. 13 (CI 15,630), D&C Red No. 7 (CI 15,850), D&CRed No. 6 (CI 15,850), D&C Yellow No. 5 (CI 19,140), D&C Red No. 36 (CI12,085), D&C Orange No. 10 (CI 45,425), D&C Yellow No. 6 (CI 15,985),D&C Red No. 30 (CI 73,360), D&C Red No. 3 (CI 45,430) and the dye orlakes based on cochineal carmine (CI 75,570) and mixtures thereof.

Representative examples of pearlescent pigments useful in the presentinvention include those selected from the group consisting of the whitepearlescent pigments such as mica coated with titanium oxide, micacoated with titanium dioxide, bismuth oxychloride, titanium oxychloride,colored pearlescent pigments such as titanium mica with iron oxides,titanium mica with ferric blue, chromium oxide and the like, titaniummica with an organic pigment of the above-mentioned type as well asthose based on bismuth oxychloride and mixtures thereof.

The nacreous pigments which may be used according to the presentinvention may be chosen from white nacreous pigments such as mica coatedwith titanium or with bismuth oxychloride, colored nacreous pigmentssuch as titanium mica with iron oxides, titanium mica with ferric blueor chromium oxide, titanium mica with an organic pigment chosen fromthose mentioned above, and nacreous pigments based on bismuthoxychloride. The nacreous pigments, if present, be present in thecomposition in a concentration ranging up to 50% by weight of the totalweight of the composition, such as from 0.1% to 20%, preferably from0.1% to 15%, including all ranges and subranges therebetween.

If present, the coloring agents may be present in the composition in aconcentration ranging up to 50% by weight of the total weight of thecomposition, such as from 0.01% to 40%, and further such as from 0.1% to30%, including all ranges and subranges therebetween. In the case ofcertain products, the pigments, including nacreous pigments, may, forexample, represent up to 50% by weight of the composition.

Embodiments without coloring agents (e.g., an inorganic or organicpigment or pearlizing agents) or with relatively low amounts of coloringagents may be suitable as primers for the skin. As used herein, a“primer” or “undercoat” is a preparatory coating put on materials (e.g.,the skin), before the application of subsequent cosmetic product layers.Priming can allow for better adhesion of these subsequent layers to thesurface and increase their durability. Priming the skin can also provideadditional protection for the material especially in terms of extendingthe wear. Priming the skin can also help to preserve the integrity ofthe subsequent cosmetic layers from fading, creasing, continued colorintensity throughout the wear, particularly those comprising thecompositions disclosed herein. Additionally, the primer can provide auniform undercoat oftentimes resulting in increased uniformity of thecolor and texture of the following coat(s). Thus, such primers may actas a base for another foundation or eye shadow composition, which mayincrease smoothness or help the other composition to better adhere. Suchprimers may also comprise mattifying agents or elastomers (e.g.,silicone elastomers).

Oil Phase

According to preferred embodiments of the present invention,compositions further comprising at least one fatty substance areprovided. Suitable fatty substances include oil(s) and/or wax(es). “Oil”means any non-aqueous medium which is liquid at ambient temperature (25°C.) and atmospheric pressure (760 mm Hg). A “wax” for the purposes ofthe present disclosure is a lipophilic fatty compound that is solid atambient temperature (25° C.) and changes from the solid to the liquidstate reversibly, having a melting temperature of more than 30° C. and,for example, more than 45° C., which can be as high as 150° C., ahardness of more than 0.5 MPa at ambient temperature, and an anisotropiccrystalline organization in the solid state. By taking the wax to itsmelting temperature, it is possible to use wax(es) by themselves ascarriers and/or it is possible to make wax(es) miscible with the oils toform a microscopically homogeneous mixture.

Suitable oils include volatile and/or non-volatile oils. Such oils canbe any acceptable oil including but not limited to silicone oils and/orhydrocarbon oils.

According to certain embodiments, the compositions of the presentinvention preferably comprise one or more volatile silicone oils.Examples of such volatile silicone oils include linear or cyclicsilicone oils having a viscosity at room temperature less than or equalto 6cSt and having from 2 to 7 silicon atoms, these silicones beingoptionally substituted with alkyl or alkoxy groups of 1 to 10 carbonatoms. Specific oils that may be used in the invention includeoctamethyltetrasiloxane, decamethylcyclopentasiloxane,dodecamethylcyclohexasiloxane, heptamethyloctyltrisiloxane,hexamethyldisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxaneand their mixtures. Other volatile oils which may be used include KF 96Aof 6 cSt viscosity, a commercial product from Shin Etsu having a flashpoint of 94° C. Preferably, the volatile silicone oils have a flashpoint of at least 40° C.

Non-limiting examples of volatile silicone oils are listed in Table 1below.

TABLE 1 Flash Point Viscosity Compound (° C.) (cSt) Octyltrimethicone 931.2 Hexyltrimethicone 79 1.2 Decamethylcyclopentasiloxane 72 4.2(cyclopentasiloxane or D5) Octamethylcyclotetrasiloxane 55 2.5(cyclotetradimethylsiloxane or D4) Dodecamethylcyclohexasiloxane (D6) 937 Decamethyltetrasiloxane (L4) 63 1.7 KF-96 A from Shin Etsu 94 6 PDMS(polydimethylsiloxane) DC 200 56 1.5 (1.5 cSt) from Dow Corning PDMS DC200 (2 cSt) from Dow Corning 87 2

Further, a volatile linear silicone oil may be employed in the presentinvention. Suitable volatile linear silicone oils include thosedescribed in U.S. Pat. No. 6,338,839 and WO03/042221, the contents ofwhich are incorporated herein by reference. In one embodiment thevolatile linear silicone oil is decamethyltetrasiloxane. In anotherembodiment, the decamethyltetrasiloxane is further combined with anothersolvent that is more volatile than decamethyltetrasiloxane.

According to certain embodiments of the present invention, thecomposition of preferably comprises one or more non-silicone volatileoils and may be selected from volatile hydrocarbon oils, volatile estersand volatile ethers. Examples of such volatile non-silicone oilsinclude, but are not limited to, volatile hydrocarbon oils having from 8to 16 carbon atoms and their mixtures and in particular branched C₈ toC₁₆ alkanes such as C₈ to C₁₆ isoalkanes (also known as isoparaffins),isohexadecane, isododecane, isodecane, and for example, the oils soldunder the trade names of Isopar or Permethyl. Preferably, the volatilenon-silicone oils have a flash point of at least 40° C.

Non-limiting examples of volatile non-silicone volatile oils are givenin Table 2 below.

TABLE 2 Compound Flash Point (° C.) Isododecane 43 Propylene glycoln-butyl ether 60 Ethyl 3-ethoxypropionate 58 Propylene glycolmethylether acetate 46 Isopar L (isoparaffin C₁₁-C₁₃) 62 Isopar H(isoparaffin C₁₁-C₁₂) 56

The volatility of the solvents/oils can be determined using theevaporation speed as set forth in U.S. Pat. No. 6,338,839, the contentsof which are incorporated by reference herein.

According to certain embodiments of the present invention, thecomposition comprises at least one non-volatile oil. Examples ofnon-volatile oils that may be used in the present invention include, butare not limited to, polar oils such as:

-   -   hydrocarbon-based plant oils with a high triglyceride content        consisting of fatty acid esters of glycerol, the fatty acids of        which may have varied chain lengths, these chains possibly being        linear or branched, and saturated or unsaturated; these oils are        especially wheat germ oil, corn oil, sunflower oil, karite        butter, castor oil, sweet almond oil, macadamia oil, apricot        oil, soybean oil, rapeseed oil, cottonseed oil, alfalfa oil,        poppy oil, pumpkin oil, sesame seed oil, marrow oil, avocado        oil, hazelnut oil, grape seed oil, blackcurrant seed oil,        evening primrose oil, millet oil, barley oil, quinoa oil, olive        oil, rye oil, safflower oil, candlenut oil, passion flower oil        or musk rose oil; or caprylic/capric acid triglycerides, for        instance those sold by the company Stearineries Dubois or those        sold under the names Miglyol 810, 812 and 818 by the company        Dynamit Nobel;    -   synthetic oils or esters of formula R₅COOR₆ in which R₅        represents a linear or branched higher fatty acid residue        containing from 1 to 40 carbon atoms, including from 7 to 19        carbon atoms, and R₆ represents a branched hydrocarbon-based        chain containing from 1 to 40 carbon atoms, including from 3 to        20 carbon atoms, with R₆+R₇≤10, such as, for example, Purcellin        oil (cetostearyl octanoate), isononyl isononanoate, octyldodecyl        neopentanoate, C₁₂ to C₁₅ alkyl benzoate, isopropyl myristate,        2-ethylhexyl palmitate, and octanoates, decanoates or        ricinoleates of alcohols or of polyalcohols; hydroxylated        esters, for instance isostearyl lactate or diisostearyl malate;        and pentaerythritol esters;    -   synthetic ethers containing from 10 to 40 carbon atoms;    -   C₈ to C₂₆ fatty alcohols, for instance oleyl alcohol, cetyl        alcohol, stearyl alcohol, and cetearly alcohol; and    -   mixtures thereof.

Further, examples of non-volatile oils that may be used in the presentinvention include, but are not limited to, non-polar oils such asbranched and unbranched hydrocarbons and hydrocarbon waxes includingpolyolefins, in particular Vaseline (petrolatum), paraffin oil,squalane, squalene, hydrogenated polyisobutene, hydrogenated polydecene,polybutene, mineral oil, pentahydrosqualene, and mixtures thereof.

In one or more embodiments, a cosmetic composition of the presentinvention may also contains at least one high viscosity ester. Examplesthereof include, but not limited to, C₁-C₃₀ monoesters and polyesters ofsugars and related materials. These esters are derived from a sugar orpolyol moiety and one or more carboxylic acid moieties. Depending on theconstituent acid and sugar, these esters can be in either liquid orsolid form at room temperature. Suitable liquid esters include, but arenot limited to: glucose tetraoleate, the glucose tetraesters of soybeanoil fatty acids (unsaturated), the mannose tetraesters of mixed soybeanoil fatty acids, the galactose tetraesters of oleic acid, the arabinosetetraesters of linoleic acid, xylose tetralinoleate, galactosepentaoleate, sorbitol tetraoleate, the sorbitol hexaesters ofunsaturated soybean oil fatty acids, xylitol pentaoleate, sucrosetetraoleate, sucrose pentaoletate, sucrose hexaoleate, sucrosehepatoleate, sucrose octaoleate, and mixtures thereof. Suitable solidesters may include, but are not limited to: sorbitol hexaester in whichthe carboxylic acid ester moieties are palmitoleate and arachidate in a1:2 molar ratio; the octaester of raffinose in which the carboxylic acidester moieties are linoleate and behenate in a 1:3 molar ratio; theheptaester of maltose wherein the esterifying carboxylic acid moietiesare sunflower seed oil fatty acids and lignocerate in a 3:4 molar ratio;the octaester of sucrose wherein the esterifying carboxylic acidmoieties are oleate and behenate in a 2:6 molar ratio; and the octaesterof sucrose wherein the esterifying carboxylic acid moieties are laurate,linoleate and behenate in a 1:3:4 molar ratio. In an embodiment, theester is a sucrose polyester in which the degree of esterification is7-8, and in which the fatty acid moieties are C18 mono- and/ordi-unsaturated and behenic, in a molar ratio of unsaturates:behenic of1:7 to 3:5. In another embodiment, the sugar polyester is the octaesterof sucrose in which there are about 7 behenic fatty acid moieties andabout oleic acid moiety in the molecule. Other materials may includecottonseed oil or soybean oil fatty acid esters of sucrose.

In one or more embodiments, the high viscosity ester comprises sucroseacetate isobutyrate. One example of a suitable sucrose acetateisobutyrate compound is SAIB-100®, commercially available from Eastman®,Kingsport, Tenn. This ester has a viscosity of about 100,000 cps at 30°C. and a refractive index of about 1.5 at 20° C.Acrylic Polymers

According to preferred embodiments, if present, the at least one oil ispresent in the compositions of the present invention in an amountranging from about 5 to about 60% by weight, more preferably from about10 to about 50% by weight, and most preferably from about 15 to about35% by weight, based on the total weight of the composition, includingall ranges and subranges within these ranges.

According to preferred embodiments of the present invention, thecompositions of the present invention further comprise at least one wax.Suitable examples of waxes that can be used in accordance with thepresent disclosure include those generally used in the cosmetics field:they include those of natural origin, such as beeswax, carnauba wax,candelilla wax, ouricoury wax, Japan wax, cork fibre wax or sugar canewax, rice wax, montan wax, paraffin wax, lignite wax or microcrystallinewax, ceresin or ozokerite, and hydrogenated oils such as hydrogenatedcastor oil or jojoba oil; synthetic waxes such as the polyethylene waxesobtained from the polymerization or copolymerization of ethylene, andFischer-Tropsch waxes, or else esters of fatty acids, such asoctacosanyl stearate, glycerides which are concrete at 30° C., forexample at 45° C.

According to particularly preferred embodiments of the presentinvention, the compositions of the present invention further include atleast one silicone wax. Examples of suitable silicone waxes include, butare not limited to, silicone waxes such as alkyl- or alkoxydimethiconeshaving an alkyl or alkoxy chain ranging from 10 to 45 carbon atoms,poly(di)methylsiloxane esters which are solid at 30° C. and whose esterchain comprising at least 10 carbon atoms, di(1,1,1-trimethylolpropane)tetrastearate, which is sold or manufactured by Heterene under the nameHEST 2T-4S; alkylated silicone acrylate copolymer waxes comprising atleast 40 mole % of siloxy units having the formula(R₂R′SiO_(1/2))_(x)(R″SiO_(3/2))_(y), where x and y have a value of 0.05to 0.95, R is an alkyl group having from 1 to 8 carbon atoms, an arylgroup, a carbinol group, or an amino group, R is a monovalenthydrocarbon having 9-40 carbon atoms, R″ is a monovalent hydrocarbongroup having 1 to 8 carbon atoms, an aryl group such as those disclosedin U.S. patent application 2007/0149703, the entire contents of which ishereby incorporated by reference, with a particular example beingC30-C45 alkyldimethylsilyl polypropylsilsesquioxane; and mixturesthereof.

According to preferred embodiments of the present invention, thecompositions of the present invention further include at least onelong-chain alcohol wax. Preferably, the at least one long-chain alcoholwax has an average carbon chain length of between about 20 and about 60carbon atoms, most preferably between about 30 and about 50 carbonatoms. Suitable examples of long-chain alcohol waxes include but are notlimited to alcohol waxes commercially available from Baker Hughes underthe Performacol trade name such as, for example, Performacol 350, 425and 550. Most preferably, the long-chain alcohol wax has a meltingtemperature range from about 93° C. to about 105° C.

According to preferred embodiments, the compositions of the presentinvention contain less than 1% wax.

According to preferred embodiments, the compositions of the presentinvention contain less than 0.5% wax.

According to preferred embodiments, the compositions of the presentinvention contain no wax.

If present, the wax or waxes may be present in an amount ranging from 1to 30% by weight relative to the total weight of the composition, forexample from 2 to 20%, and for example from 3 to 10%, including allranges and subranges therebetween.

Additional Additives

According to preferred embodiments, the compositions of the presentinvention are compositions for application to keratinous material suchas skin or lips. In accordance with these embodiments, the compositionsof the present invention can contain ingredients typically found incosmetic compositions such as, for example, water, active ingredients,humectants, surfactants and fillers. The composition of the inventioncan thus comprise any additive usually used in the field underconsideration. For example, dispersants such as poly(12-hydroxystearicacid), antioxidants, essential oils, sunscreens, preserving agents,fragrances, fillers, neutralizing agents, cosmetic and dermatologicalactive agents such as, for example, emollients, moisturizers, vitamins,essential fatty acids, surfactants, silicone elastomers, thickeningagents, gelling agents, particles, pasty compounds, viscosity increasingagents can be added. A non-exhaustive listing of such ingredients can befound in U.S. patent application publication no. 2004/0170586, theentire contents of which is hereby incorporated by reference. Furtherexamples of suitable additional components can be found in the otherreferences which have been incorporated by reference in thisapplication. Still further examples of such additional ingredients maybe found in the International Cosmetic Ingredient Dictionary andHandbook (9th ed. 2002).

A person skilled in the art will take care to select the optionaladditional additives and/or the amount thereof such that theadvantageous properties of the composition according to the inventionare not, or are not substantially, adversely affected by the envisagedaddition.

These substances may be selected variously by the person skilled in theart in order to prepare a composition which has the desired properties,for example, consistency or texture.

These additives may be present in the composition in a proportion from0% to 99% (such as from 0.01% to 90%) relative to the total weight ofthe composition and further such as from 0.1% to 50% (if present),including all ranges and subranges therebetween.

In one or more embodiments, the composition of the invention iscosmetically or dermatologically acceptable, i.e., it should contain anon-toxic physiologically acceptable medium and should be able to beapplied to the skin of human beings.

In particular, suitable gelling agents for the oil phase include, butare not limited to, lipophilic or hydrophilic clays.

The term “hydrophilic clay” means a clay that is capable of swelling inwater; this clay swells in water and forms after hydration a colloidaldispersion. These clays are products that are already well known per se,which are described, for example, in the book “Mineralogie des argiles”,S. Caillere, S. Henin, M. Rautureau, 2^(nd) edition 1982, Masson, theteaching of which is included herein by way of reference. Clays aresilicates containing a cation that may be chosen from calcium,magnesium, aluminum, sodium, potassium and lithium cations, and mixturesthereof. Examples of such products that may be mentioned include claysof the smectite family such as montmorillonites, hectorites, bentonites,beidellites and saponites, and also of the family of vermiculites,stevensite and chlorites. These clays may be of natural or syntheticorigin.

Hydrophilic clays that may be mentioned include smectite products suchas saponites, hectorites, montmorillonites, bentonites and beidellite.Hydrophilic clays that may be mentioned include synthetic hectorites(also known as laponites), for instance the products sold by the companyLaporte under the names Laponite XLG, Laponite RD and Laponite RDS(these products are sodium magnesium silicates and in particular sodiumlithium magnesium silicates); bentonites, for instance the product soldunder the name Bentone HC by the company Rheox; magnesium aluminumsilicates, especially hydrated, for instance the products sold by theVanderbilt Company under the names Veegum Ultra, Veegum HS and VeegumDGT, or calcium silicates, and especially the product in synthetic formsold by the company under the name Micro-cel C.

The term “lipophilic clay” means a clay that is capable of swelling in alipophilic medium; this clay swells in the medium and thus forms acolloidal dispersion. Examples of lipophilic clays that may be mentionedinclude modified clays such as modified magnesium silicate (Bentone GelVS38 from Rheox), and hectorites modified with a C₁₀ to C₂₂ fatty-acidammonium chloride, for instance hectorite modified withdistearyldimethylammonium chloride (CTFA name: disteardimoniumhectorite) sold under the name Bentone 38 CE by the company Rheox orBentone 38V® by the company Elementis.

In particular, among the gelling agents that may be used, mention may bemade of silica particles. Preferably, the silica particles are fumedsilica particles.

Suitable silicas include, but are not limited to, hydrophobic silicas,such as pyrogenic silica optionally with hydrophobic surface treatmentwhose particle size is less than 1 micron, preferably less than 500 nm,preferably less than 100 nm, preferably from 5 nm to 30 nm, includingall ranges and subranges therebetween. It is in fact possible to modifythe surface of silica chemically, by a chemical reaction producing adecrease in the number of silanol groups present on the surface of thesilica. The silanol groups can notably be replaced with hydrophobicgroups: a hydrophobic silica is then obtained. The hydrophobic groupscan be:

trimethylsiloxyl groups, which are notably obtained by treatment ofpyrogenic silica in the presence of hexamethyldisilazane. Silicastreated in this way are called “Silica silylate” according to the CTFA(6th edition, 1995). They are for example marketed under the references“AEROSIL R812®” by the company Degussa, “CAB-O-SIL TS-530®” by thecompany Cabot;

dimethylsilyloxyl or polydimethylsiloxane groups, which are notablyobtained by treatment of pyrogenic silica in the presence ofpolydimethylsiloxane or dimethyldichlorosilane. Silicas treated in thisway are called “Silica dimethyl silylate” according to the CTFA (6thedition, 1995). They are for example marketed under the references“AEROSIL R972®”, “AEROSIL R974®” by the company Degussa, “CAB-O-SILTS-610®”, “CAB-O-SIL TS-720®” by the company Cabot.

Suitable emollients may include, but are not limited to, the following:natural and synthetic oils such as mineral, plant and animal oils; fatsand waxes; fatty alcohols and acids, and their esters; esters and ethersof (poly)alkylene glycols; hydrocarbons such as petrolatum and squalane;lanolin alcohol and its derivatives; animal and plant triglycerides; andstearyl alcohol. Non-limiting examples include, without limitation,esters such as isopropyl palmitate, isopropyl myristate, isononylisonanoate (such as WICKENOL 151 available from Alzo Inc. of Sayreville,N.J.), C12-C15 alkyl benzoates (such as FINSOLV TN from Innospec ActiveChemicals), caprylic/capric triglycerides, pentaerythritoltetraoctanoate, mineral oil, dipropylene glycol dibenzoate, PPG-15stearyl ether benzoate, PPG-2-Myristyl Ether Propionate, ethylmethicone, diethylhexylcyclohexane, hydrocarbon-based oils of plantorigin, such as liquid triglycerides of fatty acids containing from 4 to10 carbon atoms, for instance heptanoic or octanoic acid triglycerides,sunflower oil, corn oil, soybean oil, marrow oil, grapeseed oil, sesameseed oil, hazelnut oil, apricot oil, macadamia oil, arara oil, corianderoil, castor oil, avocado oil, jojoba oil, shea butter oil, caprylylglycol; synthetic esters and ethers, especially of fatty acids, forinstance, Purcellin oil, 2-octyldodecyl stearate, 2-octyldodecylerucate, isostearyl isostearate, hydroxylated esters, for instanceisostearyl lactate, octyl hydroxystearate, octyldodecyl hydroxystearate,diisostearyl malate or triisocetyl citrate, fatty alcohol heptanoates,octanoates or decanoates, polyol esters, for instance propylene glycoldioctanoate, neopentyl glycol diheptanoate and diethylene glycoldiisononanoate, pentaerythritol esters, for instance pentaerythrityltetraisostearate, isopropyl lauroyl sarcosinate, petroleum jelly,polydecenes, hydrogenated polyisobutene such as Parleam oil, and/or themixture of n-undecane and of n-tridecane sold under the reference CetiolUT by the company BASF.

Preferably, the emollient agent(s), if present, is present in thecomposition of the present invention in amounts of active materialgenerally ranging from about 0.1% to about 20%, preferably from about0.25% to about 15%, and more preferably from about 0.5% to about 10%, byweight, based on the total weight of the composition, including allranges and subranges in between.

The composition may comprise skin active agents. Suitable active agentsinclude, for example, anti-acne agents, antimicrobial agents,anti-inflammatory agents, analgesics, anti-erythemal agents,antipruritic agents, antiedermal agents, antipsoriatic agents,antifungal agents, skin protectants, vitamins, antioxidants, scavengers,anti-irritants, antibacterial agents, antiviral agents, antiagingagents, protoprotection agents, hair growth enhancers, hair growthinhibitors, hair removal agents, antidandruff agents, anti-seborrheicagents, exfoliating agents, wound healing agents, anti-ectoparasiticagents, sebum modulators, immunomodulators, hormones, botanicals,moisturizers, astringents, cleansers, sensates, antibiotics,anesthetics, steroids, tissue healing substances, tissue regeneratingsubstances, hydroxyalkyl urea, amino acids, peptides, minerals,ceramides, biohyaluronic acids, vitamins, skin lightening agents, selftanning agents, coenzyme Q10, niacinimide, capcasin, caffeine, and anycombination of any of the foregoing.

There are also several optional adjuvants that may be included. Examplesinclude pH adjusters, emollients, humectants, conditioning agents,moisturizers, chelating agents, propellants, rheology modifiers andemulsifiers such as gelling agents, fragrances, odor masking agents, UVstabilizer, preservatives, and any combination of any of the foregoing.Examples of pH adjusters include, but are not limited to, aminomethylpropanol, aminomethylpropane diol, triethanolamine, triethylamine,citric acid, sodium hydroxide, acetic acid, potassium hydroxide, lacticacid, and any combination thereof.

Suitable conditioning agents include, but are not limited to,cyclomethicone; petrolatum; dimethicone; dimethiconol; silicone, such ascyclopentasiloxane and diisostearoyl trimethylolpropane siloxy silicate;sodium hyaluronate; isopropyl palmitate; soybean oil; linoleic acid;PPG-12/saturated methylene diphenyldiisocyanate copolymer; urea;amodimethicone; trideceth-12; cekimonium chloride; diphenyl dimethicone;propylene glycol; glycerin; hydroxyalkyl urea; tocopherol; quaternaryamines; and any combination thereof.

Suitable preservatives for skin compositions include, but are notlimited to, chlorophenesin, sorbic acid, disodiumethylenedinitrilotetraacetate, phenoxyethanol, methylparaben,ethylparaben, propylparaben, phytic acid, imidazolidinyl urea, sodiumdehydroacetate, benzyl alcohol, methylehloroisothiazolinone,methylisothiazolinone, and any combination thereof. The heat-protectivecomposition generally contains from about 0.001% to about 20% by weightof preservatives, based on 100% weight of total heat-protectivecomposition. In another aspect, the composition contains from about 0.1%to about 10% by weight of preservatives, based on 100% weight of totalheat-protective composition.

The compositions may also optionally comprise UV filters. UV filters arewell known in the art for their use in stopping UV radiation. Forexample, the UV filter may be one or more organic UV filters and/or oneor more inorganic UV filters. Non-limiting examples of UV filtersinclude:

-   -   i. Sparingly soluble UV filters (not appreciably soluble in        either water or oil) such as Methylene Bis-Benzotriazolyl        Tetramethylbutylphenol, Tris-Biphenyl Triazine, Methanone,        1,1′-(1,4-piperazinediyl)bis[1-[2-[4-(diethylamino)-2-hydroxybenzoyl]phen-yl]-and        mixtures thereof.    -   ii. Oil soluble organic UV filters (at least partially soluble        in oil or organic solvent), such as Bis-Ethylhexyloxyphenol        Methoxyphenyl Triazine, Butyl Methoxydibenzoylmethane (BMBM),        Oxybenzone, Sulisobenzone, Diethylhexyl Butamido Triazone (DBT),        Drometrizole Trisiloxane, Ethylhexyl Methoxycinnamate (EHMC),        Ethylhexyl Salicylate (EHS), Ethylhexyl Triazone (EHT),        Homosalate, Isoamyl p-Methoxycinnamate, 4-Methylbenzylidene        Camphor, Octocrylene (OCR), Polysilicone-15, and Diethylamino        Hydroxy Benzoyl Hexyl Benzoate (DHHB);    -   iii. Inorganic UV filters such as titanium oxide and zinc oxide,        iron oxide, zirconium oxide and cerium oxide; and    -   iv. Water soluble UV filters such as Phenylbenzimidazole        Sulfonic Acid (PBSA), Sulisobenzone-sodium salt, Benzydilene        Camphor Sulfonic Acid, Camphor Benzalkonium Methosulfate,        Cinoxate, Disodium Phenyl Dibenzylmidazole Tetrasulfonate,        Terephthalylidene Dicamphor Sulfonic Acid, PABA, and PEG-25        PABA.

In some instances, the UV filter is one or more of: a para-aminobenzoicacid derivative, a salicylic derivative, a cinnamic derivative, abenzophenone or an aminobenzophenone, an anthranillic derivative, a β,β-diphenylacrylate derivative, a benzylidenecamphor derivative, aphenylbenzimidazole derivative, a benzotriazole derivative, a triazinederivative, a bisresorcinyl triazine, an imidazoline derivative, abenzalmalonate derivative, a 4,4-diarylbutadiene derivative, abenzoxazole derivative, a merocyanine, malonitrile or a malonatediphenyl butadiene derivative, a chalcone, or a mixture thereof.

Suitable UV filters can include broad-spectrum UV filters that protectagainst both UVA and UVB radiation, or UV filters that protect againstUVA or UVB radiation. In some instances, the one or more UV filters maybe methylene bis-benzotriazolyl tetramethylphenol, diethylaminohydroxybenzoyl hexyl benzoate, coated or uncoated zinc oxide, ethylhexylmethoxycinnamate, isoamyl methoxycinnamate, homosalate ethyl hexylsalicylate, octocrylene, polysilicone-15, butyl methoxydibenzoylmethane,menthyl anthranilate, and ethylhexyl dimethyl PABA.

Furthermore, combinations of UV filters may be used. For example, thecombination of UV filters may be octocrylene, avobenzone (butylmethoxydibenzoylmethane), oxybenzone (benzophenone-3), octisalate(ethylhexyl salicylate), and homosalate, as described in U.S. Pat. No.9,107,843, which is incorporated herein by reference in its entirety.

Methods

According to preferred embodiments of the present invention, methods oftreating, caring for and/or making up keratinous material, such as skinor lips, by applying compositions of the present invention to thekeratinous material in an amount sufficient to treat, care for and/ormake up the keratinous material are provided. Preferably, “making up”the keratin material includes applying at least one coloring agent tothe keratin material in an amount sufficient to provide color to thekeratin material.

According to yet other preferred embodiments, methods of enhancing theappearance of keratinous material by applying compositions of thepresent invention to the keratinous material in an amount sufficient toenhance the appearance of the keratinous material are provided.

According to preferred embodiments of the present invention, methods ofapplying compositions of the present invention to a keratinous material(for example, skin or lips) comprising mixing or blending thecomposition so that the immiscible components are temporarily miscible,and applying the composition comprising the temporarily misciblecomponents to the keratinous material are provided. In one or moreembodiments, composition may be mixed in a mixing pack or may be mixedby hand. Subsequent to application to the keratinous material, thecomponents separate to form a multilayer structure on the keratinousmaterial.

According to preferred embodiments of the present invention, kitscomprising (1) at least one container; (2) at least one applicator; and(3) at least one cosmetic composition capable of forming a multilayerstructure after application to a keratinous material, wherein thecomposition comprises at least two immiscible components prior toapplication.

In accordance with the preceding preferred embodiments, the compositionsof the present invention are applied topically to the desired area ofthe keratin material in an amount sufficient to treat, care for and/ormake up the keratinous material, to cover or hide defects associatedwith keratinous material, skin imperfections or discolorations, or toenhance the appearance of keratinous material. The compositions may beapplied to the desired area as needed, preferably once daily, and thenpreferably allowed to dry before subjecting to contact such as withclothing or other objects. Preferably, the composition is allowed to dryfor about 4 minutes or less, more preferably for about 2 minutes orless.

Also in accordance with the preceding preferred embodiments,compositions are preferably contained in a suitable container forcosmetic compositions. Suitable shapes of such containers include, butare not limited to, any geometric shape such as, for example, square,rectangular, pyramidal, oval, circular, hemispherical, etc. Further, thecontainer may be made of flexible or inflexible material.

Similarly, any applicator suitable for application of cosmeticcompositions can be used in accordance with the present invention, withsuitable examples of types of applicators including, but not limited to,a brush, stick, pad, roller ball, etc.

Preferably, either (1) the container is capable of mixing or blendingthe composition of the present invention so that the immisciblecomponents are temporarily miscible; (2) the applicator is capable ofmixing or blending the composition of the present invention so that theimmiscible components are temporarily miscible; or (3) the container andthe applicator working together are capable of mixing or blending thecomposition of the present invention so that the immiscible componentsare temporarily miscible in accordance with the preceding preferredembodiments. For example, a flexible container by virtue of itsflexibility could create sufficient forces when manipulated totemporarily mix or blend the composition of the present invention sothat the immiscible components are temporarily miscible; an applicatorby virtue of its design could create sufficient forces when withdrawnfrom the container to temporarily mix or blend the composition of thepresent invention so that the immiscible components are temporarilymiscible; or (3) an inflexible container and an applicator by virtue oftheir synergistic design elements could create sufficient forces whenthe applicator is withdrawn from the container to temporarily mix orblend the composition of the present invention so that the immisciblecomponents are temporarily miscible.

According to preferred embodiments, the compositions of the presentinvention are lip compositions for application to lips such aslipsticks, lip gloss or lip balms. In accordance with these embodiments,the compositions of the present invention can contain ingredientstypically found in lip compositions such as, for example, coloringagents, waxes, and gelling agents. Further, the compositions can containwater or be anhydrous. Also, the compositions can be solid or non-solid.

According to preferred embodiments, the compositions of the presentinvention are skin compositions for application to skin such asfoundations, moisturizers, sunscreens, blush, eyeshadows, etc. Inaccordance with these embodiments, the compositions of the presentinvention can contain ingredients typically found in skin compositionssuch as, for example, coloring agents, active ingredients, humectants,surfactants and fillers. Further, the compositions can contain water orbe anhydrous. Also, the compositions can be solid or non-solid.

According to preferred embodiments, the compositions of the presentinvention are hair compositions for application to hair such asshampoos, conditioners, styling mousses and dyes. In accordance withthese embodiments, the compositions of the present invention can containingredients typically found in hair compositions such as, for example,coloring agents, surfactants, moisturizers, and active agents. Further,the compositions can contain water or be anhydrous. Also, thecompositions can be in various forms such as liquid, foam, and paste.

According to preferred embodiments, the compositions of the presentinvention are nail compositions for application to nails such as primercompositions, color compositions or topcoat compositions. In accordancewith these embodiments, the compositions of the present invention cancontain ingredients typically found in nail compositions such as, forexample, coloring agents, polymerizable compounds, and solvents.Further, the compositions can contain water or be anhydrous.

According to preferred embodiments, the compositions of the presentinvention are eyelash compositions for application to eyelashes such asprimers, mascaras and topcoats. In accordance with these embodiments,the compositions of the present invention can contain ingredientstypically found in eyelash compositions such as, for example, coloringagents, waxes, and gelling agents. Further, the compositions can containwater or be anhydrous. Also, the compositions can be of any form typicalfor such compositions such as, for example, emulsion or dispersion.

Unless otherwise indicated, all numbers expressing quantities ofingredients, reaction conditions, and so forth used in the specificationand claims are to be understood as being modified in all instances bythe term “about.” Accordingly, unless indicated to the contrary, thenumerical parameters set forth in the following specification andattached claims are approximations that may vary depending upon thedesired properties sought to be obtained by the present invention.

Notwithstanding that the numerical ranges and parameters setting forththe broad scope of the invention are approximations, the numericalvalues set forth in the specific examples are reported as precisely aspossible. Any numerical value, however, inherently contain certainerrors necessarily resulting from the standard deviation found in theirrespective measurements. The following examples are intended toillustrate the invention without limiting the scope as a result. Thepercentages are given on a weight basis.

EXAMPLES Example 1—Foundation Testing

Preparation

Foundation examples Inventive 2, Comparative 3 and Comparative 4 wereprepared using a high speed mixer. To a high speed mixer cup, allpolymers were added. The sample was mixed at 2500-3500 RPM untilhomogenous. The samples typically were opaque and not clear, andhomogeneity was deciphered by the sample smoothness. To the freshlymixed sample, pigments, pigment dispersions, and any other particleswere added in addition to the QS solvent. The sample was additionallymixed at 2500-3500 RPM until homogenous. Ingredients are as shown in thetable below.

Comparative 1 is a commercially available product. Comparative 1 isconsidered to be comparative because it does not contain a siliconecompound and the silicone resin that is used has a high T_(g).

Comparative 3 is considered to be comparative because it does notcontain any film forming agents (i.e., a Component A).

Comparative 4 is considered to be comparative because it does notcontain a silicone compound (i.e., a Component B).

Wear Test

Foundation samples were casted onto Byko-Charts Black Scrub PanelsP122-10N (6.50×17.00 inches) using a 3 mil wet drawdown bar. Films wereallowed to dry for a minimum of five hours. Samples were then abradedusing an automatic drawdown machine (Gardco Automatic Drawdown Machine)equipped with Velcro (¾″ white 010 PSA 0172) loop side pieces adhered tothe lowest bar. Contact between the Velcro adhered bar and the filminterface was made and then the bar was automatically dragged across thesample five times (one direction is considered drag across). Sampleswere then evaluated for removal of product in which a rating of 1 isminimal removal, 2 is intermediate removal, and 3 is complete removal.

Self-Leveling Test

Samples were evaluated for their dried film properties. Samples werecasted onto a Byko-Charts Black Scrub Panels P122-10N (6.50×17.00inches) using a 3 mil wet drawdown bar at room temperature. Samples wereallowed to dry for a minimum of 5 hours. After drying, samples werevisually and manually evaluated for phase separation and self-levelingproperties. In order to assess the phase separation, films were agitatedwith a gloved index finger by lightly rubbing one stroke across thesample interface. If samples could be roughened it was documented andthey were further assessed for recovery of the film by self-leveling.Samples were allowed to rest for a minimum of a 24 hour period and thenvisually reassessed for interface quality and if there was any level ofrecovery. Images were also captured of the samples prior to roughening,at initial roughening, and at 24 hours after roughening. After the 24hour period, it was documented if the sample showed signs of recovery ornot.

Compar- Inventive Compar- Compar- RM Name ative 1 2 ative 3 ative 4Polypropyl Silicone Resin 14.58 0 14.58 silisequioxane Containing Resin(72% Technology Active in Isododecane) Silicone Acrylate 11.25 0 11.25Polymer¹ 40% Active in Isododecane) Dimethiconol² 5 5 0 Pigment 12.0212.02 12.02 Isododecane QS QS QS Total 100 100 100 Film Disrupted No YesYes-partly Slightly removed Self-Leveling No Yes No Yes Property? Weartest- 2 1 2 2 Abrasion Score 1 = Kp550, Shin Etsu 2 = 1515 Silicone Gum,Dow Corning

As can be seen from the table above, the only composition to allow filmdisruption and exhibit self-healing was Inventive 1. Comparative 1 didnot allow for film disruption, and thus would not exhibit self-healing.Such film setting means that if disturbed enough, the film may flake, ahighly undesirable quality in foundation. Inventive 2 allowed for filmdisruption, and then leveled to the point where disruption could nolonger be detected. Comparative 3 allowed for film disruption, but wasalso partly removed, again an undesired effect in a foundation.Comparative 4 allowed for slight film disruption, and exhibited someself-leveling, but not to the extent of Inventive 1. Thus, Inventive 1was the foundation sample to exhibit the greatest degree ofself-leveling.

As can also be seen from the table above, only Inventive 2 scored a 1 onthe wear test, meaning it was the only composition exhibiting minimalremoval. All other comparative samples scored a 2, corresponding tointermediate removal.

These results show the nexus between having both film forming agent andsilicone compound and achieving good wear self-healing properties.Inventive 2 and Comparative 3 differ in that Comparative 3 does not haveany film forming agents, with isododecane increased to maintain the samelevels of pigment and dimethiconol. Similarly, Inventive 2 andComparative 4 differ in that Comparative 4 does not containdimethiconol, again with isododecane increased to maintain the samelevels of pigment and film forming agents. Thus, Inventive 2 can bedirectly compared to Comparative 3 to see the effect of removing thefilm forming agents, and Inventive 2 can be directly compared toComparative 4 to see the effect of removing the silicone compounds.

Indeed, the results demonstrate that self-healing and good wear areexhibited only when both Components A and B are present (i.e., asynergistic effect). Comparative 3 was partly removed during filmdisruption, exhibited no self-healing and scored a 2 in the wear test.Comparative 4 was slightly disrupted, exhibited self-healing, and alsoonly scored a 2 in the wear test. Inventive 2 outperformed Comparative 3and 4 in all respects, thereby showing both components are required, andthat they have a synergistic effect compared to composition with onlyone of Component A or B.

Example 2—Primer Testing

Preparation

Primer examples were prepared using a high speed mixer. To a high speedmixer cup, all polymers were added. The sample was mixed at 2500-3500RPM until homogeneous. The samples were opaque, not clear and thehomogeneity was assessed by the sample smoothness. To the freshly mixedsamples, filler particles were added. The sample was again mixed at2500-3500 RPM until homogeneous.

Comparative 6 is a commercially available product.

Self-Leveling Test

Samples were evaluated for their dried film properties. Samples werecasted onto a Byko-Charts Black Scrub Panels P122-10N (6.50×17.00inches) using a 3 mil wet drawdown bar at room temperature. Samples wereallowed to dry for a minimum of 5 hours. After drying, samples werevisually and manually evaluated for phase separation and self-levelingproperties. In order to assess the phase separation, films were agitatedwith a gloved index finger by lightly rubbing one stroke across thesample interface. If samples could be roughened it was documented andthey were further assessed for recovery of the film by self-leveling.Samples were allowed to rest for a minimum of a 24 hour period and thenvisually reassessed for interface quality and if there was any level ofrecovery. Images were also captured of the samples prior to roughening,at initial roughening, and at 24 hours after roughening. After the 24hour period, it was documented if the sample showed signs of recovery ornot.

Bulk Phase Separation Assessment

All samples were visually assessed for homogeneity, phase separation,and any additional visual attributes. These evaluations were conductedafter the bulk formula was allowed to rest at room temperature for 24hours after mixing or agitation. If the bulk appeared phase separated ornot, the sample was noted.

Adhesion Assessment

Samples were casted onto a BYK Byko-Charts Black Scrub Panels P122-10N(6.50×17.00 inches) using a 3 mil wet drawdown bar at room temperature.Samples were allowed to dry for a minimum of 24 hours. A sheet of ASTMCross hatch tape (Permacel 99/PA-28060/51596) was applied onto the filmand patted down to ensure contact with the film. Tape was removed at 180degree angle and visually assessed for removal of product. The productwas assessed on a three point scale where a 1 is no removal of product a2 is partial removal of product and a 3 is complete removal of product.

Visual Assessment of Eye Shadow on Top of Primer

Samples were casted onto a BYK Byko-Charts Black Scrub Panels P122-10N(6.50×17.00 inches) using a 3 mil wet drawdown bar at room temperature.Samples were allowed to dry for a minimum of 24 hours. Following thefilm setting, an eye shadow was applied on top of the primer sample. Theproduct was visually assessed for color intensity and the colorconsistency to the bulk product. Color intensity was assessed accordinga 3 point scale where a 1 is very high intensity a 2 is intermediateintensity and a 3 is low intensity. Color consistency was rated based ofcolor pay off versus the bulk color of the eye shadow where a 1 is verysimilar to the bulk a 2 is somewhat similar and a 3 is very dissimilarto the bulk.

Raw Material Inventive 5 Comparative 6 Polypropylsilisquoxane (72% 44On-Market Active in Isododecane) Technology Dimethiconol¹ 22 containingMQ Isododecane (QS) 33 Silicone Resin Silica Silylate (Aerogel)² 1Technology Total 100 Bulk Phase Separation Yes NA Film Disrupted? YesYes (Sample was removed from substrate) Self-Leveling? Yes No AdhesionAssessment 1 3 Visual Assessment of Color 1 2 Intensity VisualAssessment of Color 1 2 Consistency to Bulk 1 = 1515 Silicone Gum, DowCorning 2 = DOW CORNING VM-2270 AEROGEL FINE PARTICLES

As seen in the table above, on-market commercially available Comparative6 did not perform as well as Inventive 5 with respect to adhesionassessment, color intensity or color consistency. Moreover, Inventive 5exhibited self-leveling properties after disruption while Comparative 6was partly removed during disruption, and did not self-level over time.

Example 3—Anhydrous Compositions

Sample Preparation: Compositions were prepared using a high speed mixer.To a high speed mixer cup, all polymers were added. The sample was mixedat 2500-3500 RPM until homogenous. The samples typically were opaque andnot clear, and homogeneity was deciphered by the sample smoothness. Tothe freshly mixed sample, pigments, pigments dispersions, and any otherparticles were added in addition to the QS solvent. The sample wasadditionally mixed at 2500-3500 RPM until homogenous.

Film disruption and recovery: Samples were evaluated for their driedfilm properties. Samples were casted onto a BYK Opacity Chart (#2812)using a 3 mil wet drawdown bar at room temperature. Samples were allowedto dry for a minimum of 5 hours. After drying, samples were visually andmanually evaluated for phase separation and self-leveling properties. Inorder to assess the phase separation, films were agitated with a glovedfinger. If samples could be roughened it was documented and they werefurther assessed for recovery of the film by self-leveling. Samples wereallowed to rest for a minimum of a 24 hour period and then visuallyreassessed for interface quality and if there was any level of recovery.Images were also captured of the samples prior to roughening, at initialroughening, and at 24 hours after roughening. After the 24 hour period,it was documented if the sample showed signs of recovery or not.

Water Contact Angle: To a BYK Opacity Chart (#2812) a 3 mil wet drawdownbar was used to cast a film. Films were allowed to dry for at least 48hours prior to measurements. All contact angle measurements werecaptured using a tensiometer. A 2-3 microliter sessile drop was placedonto the casted films, and mean contact angle values were captured afterten seconds. For each sample a minimum of three contact angle valueswere taken, and an average is depicted on the table below.

The compositions in the below table were prepared and tested accordingto protocols set forth above. As can be seen, Inventive example 1exhibited self-leveling properties after agitation. Moreover the watercontact angle of Inventive example 1 was similar to that of Comparativeexample 3.

Inventive Comparative Comparative 1 2 3 Sucrose Acetate Isobutyrate 1010 0 (SAIB) Dimethicone¹ 10 0 10 Dimethiconol² 5 0 5 Pigment 3 3 3Isododecane 72 87 82 Total 100 100 100 Roughened? Yes No Yes Recovered?Yes No No Water Contact Angle Average 122.014 102.0675 129.068 at 10seconds ¹XIAMETER PMX-200 SILICONE FLUID 1000 CS ²Dow Corning 1515 SiGum

The compositions in the below table were prepared and tested accordingto protocols set forth above. As can be seen, Inventive example 1exhibited self-leveling properties after agitation. Moreover the watercontact angle of Inventive example 1 was similar to that of Comparativeexample 3.

Example 4—Lip Oil Composition Preparations

Lip oil examples were prepared using a high speed mixer. To a high speedmixer cup, all polymers were added. The sample was mixed at 2500-3500RPM until homogenous. The samples typically were opaque and not clear,and homogeneity was deciphered by the sample smoothness. To the freshlymixed sample, pigments, pigments dispersions, and any other particleswere added in addition to the QS solvent. The sample was additionallymixed at 2500-3500 RPM until homogenous.

Testing Protocols

Gloss Testing

Samples were evaluated for their gloss value using a gloss meter. Samplefilms were prepared by using a 3 mil wet drawdown bar to deposit a filmonto BYK Opacity Chart (#2812). Films were allowed to dry for a minimumof 1 hour and then were evaluated for their gloss values using a BYKMicro-TRI-Gloss meter. From the values captured, the 60 degree value wasreported. A value of less than 10 GU was considered to be low gloss; avalue of 10-69 GU was considered to be medium gloss; and a value of 70GU or greater was considered to be high gloss.

Transfer-Resistance: Kiss Test

Samples were tested for their resistance to transfer. The samples wererespectively applied by a subject and allowed to dry for 15 minutes.Following the 15 minute dry time, each subject kissed their clean backhand and an image was captured to assess level of transfer. For fulltransfer, a score was given of 3, while somewhat transfer was given ascore of 2, and little to no transfer was given a score of 1.

Self-Leveling Testing

Samples were evaluated for their dried film properties. Samples werecasted onto a BYK Opacity Chart (#2812) using a 3 mil wet drawdown barat room temperature. Samples were allowed to dry for a minimum of 5hours. After drying, samples were visually and manually evaluated forphase separation and self-leveling properties. In order to assess thephase separation, films were agitated with a gloved finger with force of35-55 grams of force. In order to insure the same force was applied forall samples, the contrast card was placed on an scale, a weight itplaces to hold down the film and the scale is tarred. Then a glovedindex finger was used to pass across the sample. The pressure appliedwas sustained within 35-55 g of force. If samples could be roughened itwas documented and they were further assessed for recovery of the filmby self-leveling. Samples were allowed to rest for a minimum of a 24hour period and then visually reassessed for interface quality and ifthere was any level of recovery. Images were also captured of thesamples prior to roughening, at initial roughening, and at 24 hoursafter roughening. After the 24 hour period, it was documented if thesample showed signs of recovery or not.

Bulk Phase Separation

All samples were visually assessed for homogeneity, phase separation,and any additional visual attributes. These evaluations were conductedafter the bulk formula was allowed to rest at room temperature for aminimum of 1 hour-72 hours after mixing or agitation.

Inventive and Comparative Compositions

The compositions in the following table were prepared and testedaccording to protocols set forth above. As can be seen, Inventiveexamples 3 and 5 had improved transfer resistance relative to the marketcomparative example, as well as a high gloss value. In addition thesamples phase separated in bulk, and the inherent self-leveling propertywas also seen within this samples.

Comparative Comparative Inventive Comparative INCI NAME 1 2 3 4Polypropylsilisquioxane 13.89 0 13.89 On Market Hydrocarbon (72% Activein Isododecane) Dimethiconol¹ 0 4.5 4.5 Based Lip Dimethicone² 0 4.5 4.5Oil Tint Dimethicone³ 0 36 36 Isododecane QS QS QS Pigments 0.83 0.830.83 Total 100 100 100 Non-volatile 1:0 0:1 1:4.5 N/A Component A:Non-volatile Component B* Active Concentration 10 0 10 Component AActive Concentration 0 45 45 Component B 60 Degree Gloss Value 39.9 ±12.5 69.4 ± 0.6 70. 2 ± 0.7 82.34 Film roughened? No Yes Yes YesSelf-Leveling No Yes Yes Yes Kiss Test 1 2.25 1.25 2.5 Bulk PhaseSeparation No No Yes No Inventive 5 Comparative 6 Comparative 7Polypropylsilisquioxane 13.89 13.89 0 (72% Active in Isododecane) KP550Acrylate/ 18.75 18.75 0 dimethicone copolymer (40% Active inIsododecane) Dimethiconol¹ 4.5 0 4.5 Dimethicone² 4.5 0 4.5 Dimethicone³36 0 36 Isododecane QS QS QS Pigments 0.83 0.83 0.83 Total 100 100 100Non-volatile 1:2.57 1:0 0:1 Component A: Non-volatile Component B*Active Concentration 17.5 17.5 0 Component A Active Concentration 45 045 Component B 60 Degree Gloss Value 70.1 ± 0.2 57.9 ± 3 69.4 ± 0.6 Filmroughened? Yes No Yes Self-Leveling Yes No Yes Kiss Test 1.5 1 2 BulkPhase Separation Yes No Somewhat- pigment crashed out. ³Dow Corning 1515Si Gum 4. XIAMETER PMX-200 SILICONE FLUID 1,000,000 CS 5. XIAMETERPMX-200 SILICONE FLUID 1000 CS *Not including pigments.

Example 5—Lip Gloss Preparations

Lip gloss compositions were prepared using a high speed mixer. To a highspeed mixer cup, all polymers were added. The sample was mixed at2500-3500 RPM until homogenous. The samples typically were opaque andnot clear, and homogeneity was deciphered by the sample smoothness. Tothe freshly mixed sample, pigments, pigments dispersions, and any otherparticles were added in addition to the QS solvent. The sample wasadditionally mixed at 2500-3500 RPM until homogenous.

Testing Protocols

Transfer-Resistance: Kiss Test

Samples were tested for their resistance to transfer. The samples wererespectively applied by a subject and allowed to dry for 15 minutes.Following the 15 minute dry time, each subject kissed their clean handand an image was captured to assess level of transfer. For fulltransfer, a score was given of 3, while somewhat transfer was given ascore of 2, and little to no transfer was given a score of 1.

Tack Testing

To assess sample tackiness, a thin film of each sample was placed on aBYK Opacity Chart (#2812) using a 3 mil wet draw down bar. The film wasallowed to dry for a minimum of 1 hour and was measured for its peakforce using a texture analyzer. A ½″ stainless steel ball probe wasused, and a standard adhesive test was conducted in which the probe wasapplied, at a rate of 0.5 mm/sec, on the sample at 250 g of force for aminimum of 10 seconds. The probe was removed from the sample at a rateof 10 mm/sec. The peak force tack was captured in the reading. Typicallya minimum of three measurements were conducted and an average peak forcetack is noted. All measurements were conduction at ambient temperatures.

Gloss Testing

Samples were evaluated for their gloss value using a gloss meter. Samplefilms were prepared by using a 3 mil wet drawdown bar to deposit a filmonto BYK Opacity Chart (#2812). Films were allowed to dry for a minimumof 1 hour and then were evaluated for their gloss values using a BYKMicro-TRI-Gloss meter. From the values captured, the 60 degree value wasreported. A value of less than 10 GU was considered to be low gloss; avalue of 10-69 GU was considered to be medium gloss; and a value of 70GU or greater was considered to be high gloss.

Self-Leveling Testing

Samples were evaluated for their dried film properties. Samples werecasted onto a BYK Opacity Chart (#2812) using a 3 mil wet drawdown barat room temperature. Samples were allowed to dry for a minimum of 5hours. After drying, samples were visually and manually evaluated forphase separation and self-leveling properties. In order to assess thephase separation, films were agitated with a gloved finger with force of35-55 grams of force. In order to insure the same force was applied forall samples, the contrast card was placed on an scale, a weight itplaces to hold down the film and the scale is tarred. Then a glovedindex finger was used to pass across the sample. The pressure appliedwas sustained within 35-55 g of force. If samples could be roughened itwas documented and they were further assessed for recovery of the filmby self-leveling. Samples were allowed to rest for a minimum of a 24hour period and then visually reassessed for interface quality and ifthere was any level of recovery. Images were also captured of thesamples prior to roughening, at initial roughening, and at 24 hoursafter roughening. After the 24 hour period, it was documented if thesample showed signs of recovery or not.

Bulk Phase Separation

All formulas were visually assessed for homogeneity, phase separation,and any additional visual attributes. These evaluations were conductedafter the bulk formula was allowed to rest at room temperature for aminimum of 1 hour and up to 72 hours after mixing or agitation.

Inventive and Comparative Compositions

The compositions in the following table were prepared and testedaccording to protocols set forth above. As can be seen, Inventiveexample 10 had improved transfer resistance relative to the marketcomparative example, as well as a high gloss value. Moreover the samplehad a low tack value. In addition the sample was phase separated inbulk, and the inherent self-leveling property was also seen within thissample.

Comparative Comparative Inventive Comparative INCI NAME 8 9 10 11Polypropyl- 14.2 0 14.2 Market silisquioxane Product (72% Active in LongIsododecane) Wear Dimethiconol¹ 0 8.2 8.2 Lipgloss Dimethicone² 0 4.14.1 Acrylates Dimethicone³ 0 28.6 28.6 Copolymer Isododecane OS QS QSTechnology Pigments 3 3 3 Total 100 100 100 NA Non-volatile 1:0 0:11:4.02 Component A: Non-volatile Component B* Active 10.22 0 10.22Concentration Component A Active 0 40.9 40.9 Concentration Component BKiss Test 2 2 3 60 Degree Gloss 3.5 ± 0.5 68.1 ± 0.7   70 ± 0.2  78 ±1.3 Value Film roughened? No Yes Yes Yes Self- Leveling No Somewhat. YesNo Tack 21.07 ± 6.6  12.33 ± 1.3   1.77 ± 0.21 36.63 ± 4.8  Bulk PhaseNo No Yes No Separation * Not including pigments. ¹Dow Corning 1515 SiGum ²XIAMETER PMX-200 SILICONE FLUID 1,000,000 CS ³XIAMETER PMX-200SILICONE FLUID 1000 CS

Example 6—Water-Containing Formulations

Inventive 1 Preparation

Inventive 1 was prepared using a high speed mixer. The ingredients ofInventive 1 are shown in the Table below. To a high speed mixer cup, allpolymers were added. The sample was mixed at 2500-3500 RPM untilhomogenous. The samples typically were opaque and not clear, andhomogeneity was deciphered by the sample smoothness. To the freshlymixed sample, pigments, pigments dispersions, and any other particleswere added in addition to the QS solvent and water. The sample wasadditionally mixed at 2500-3500 RPM until homogenous.

Comparative 2 is a Commercially Available Product.

Bulk Phase Separation Assessment

All samples were visually assessed for homogeneity, phase separation,and any additional visual attributes. These evaluations were conductedafter the bulk formula was allowed to rest at room temperature for 24hours after mixing or agitation. If the bulk appeared phase separatedthe sample was noted with PS and if the sample appeared homogenous itwas noted with an H.

Self-Leveling Test

Samples were evaluated for their dried film properties. Samples werecasted onto a BYK Opacity Chart (#2812) using a 3 mil wet drawdown barat room temperature. Samples were allowed to dry for a minimum of 5hours. After drying, samples were visually and manually evaluated forphase separation and self-leveling properties. In order to assess thephase separation, films were agitated with a gloved index finger bylightly rubbing one stroke across the sample interface. If samples couldbe roughened it was documented and they were further assessed forrecovery of the film by self-leveling. Samples were allowed to rest fora minimum of a 24 hour period and then visually reassessed for interfacequality and if there was any level of recovery. Images were alsocaptured of the samples prior to roughening, at initial roughening, andat 24 hours after roughening. After the 24 hour period, it wasdocumented if the sample showed signs of recovery or not.

Transfer-Resistance: Kiss Test

Samples were tested for their resistance to transfer. The samples wererespectively applied by a subject and allowed to dry for 15 minutes.Following the 15 minute dry time, each subject kissed their clean backhand and an image was captured to assess level of transfer. For fulltransfer, a score was given of 3, while somewhat transfer was given ascore of 2, and little to no transfer was given a score of 1.

Gloss Testing Samples were evaluated for their gloss value using a glossmeter. Sample films were prepared by using a 3 mil wet drawdown bar todeposit a film onto BYK Opacity Chart (#2812). Films were allowed to dryfor a minimum of 1 hour and then were evaluated for their gloss valuesusing a BYK Micro-TRI-Gloss meter. From the values captured, the 60degree value was reported.

The results of the above tests are shown in the Table below.

Liquid Lip Color Comparative 2 On Market Inventive Gloss/Tint INCI NAME1 Product Base Polypropylsilisquioxane (72% 23.23 Active in Isododecane)Phase Acrylate/dimethicone copolymer 19.49 (40% Active in Isododecane)¹Silicone Dimethiconol² 2.32 Phase Dimethicone (1 million cst)³ 1.57Dimethicone (1000 cst) ⁴ 11.54 Isododecane 12.37 Water 24.98 Pigments4.5 Total 100 Kiss Test 1 3 60 Degree Gloss Unit 68.2 ± 0.1 47.5 ± 0.4Film Roughened? Yes Yes Self- Leveling Yes No Bulk Phase Separation PSN/A ¹Shinetsu KP55 ²Dow Corning 1515 Gum ³Dow Corning Xiameter PMX-2001000 CS ⁴ Dow Corning Xiameter PMX-200 1,000,000 CSAs can be seen from the results in the Table above, Inventive 1 providesbetter self-leveling properties as compared to the commercial product.

Example 7—Sample Formulations

Liquid Lipstick

Amount INCI Name (%) Base phase Silicone 60 Acrylate (50% Active inIsododecane) Silicone phase Dimethiconol 2 Dimethicone (1 5 million cst)Dimethicone 13 (1000 cst) Isododecane QS Pigments 6 Total 100

Liquid Lipsticks

Amount Amount Amount INCI NAME (%) (%) (%) Base Silicone Acrylate (50%40 40 40 Phase Active in Isododecane) Silicone Dimethiconol 15 0 2 PhaseDimethicone (1 million cst) 0 15 5 Dimethicone (1000 cst) 0 0 13Isododecane QS QS QS Pigments 6 6 6 Total 100 100 100

Liquid Lipsticks

Amount Amount Amount INCI NAME (%) (%) (%) Base Polypropylsilisquioxane(72% 29.16 31 38.89 Phase Active in Isododecane) (40% Active inIsododecane) Silicone Dimethiconol 10 3.1 0 Phase Dimethicone (1 millioncst) 0 2.1 0 Dimethicone (1000 cst) 0 0 13 Isododecane QS QS QS Pigments6 6 6 Total 100 100 100

Liquid Lipstick

INCI NAME Amount (%) Amount (%) Base Polypropylsilisquioxane 55.56 55.56Phase (72% Active in Isododecane) Silicone Dimethiconol 10 2 PhaseDimethicone (1 million 0 5 cst) Dimethicone (1000 cst) 0 13 IsododecaneQS QS Pigments 6 6 Total 100 100

Lip Gloss

INCI NAME Amount (%) Amount (%) Base Silicone Acrylate (50% Active 50 0Phase in Isododecane Polypropylsilisquioxane (72% 0 14.2 Active inIsododecane) Acrylate/dimethicone 0 0 copolymer (40% Active inIsododecane) Silicone Dimethiconol 5.63 8.2 Phase Dimethicone (1 millioncst) 3.75 4.1 Dimethicone (1000 cst) 28.13 28.6 Isododecane QS QSPigments 3 3 Total 100 100

Lip Oil

INCI NAME Amount (%) Amount (%) Base Silicone Acrylate (50% Active 50 0Phase in Isododecane Polypropylsilisquioxane (72% 0 13.89 Active inIsododecane) Acrylate/dimethicone 0 18.75 copolymer (40% Active inIsododecane) Silicone Dimethiconol 3.75 4.5 Phase Dimethicone (1 millioncst) 2.5 4.5 Dimethicone (1000 cst) 18.75 36 Isododecane QS QS Pigments0.025 0.83 Total 100 100

Foundation

Foundation INCI NAME Amount (%) Base Polypropylsilisquioxane (72% 14.58Phase Active in Isododecane) Acrylate/dimethicone 11.25 copolymer (40%Active in Isododecane) Silicone Dimethicone (1000 cst) 5 PhaseDimethiconol 9 Pigments 12.02 Dimethicone/bis-isobutyl ppg- 10 20crosspolymer (17% Active in Isododecane) Isododecane 38.15 Total 100

Hair Composition

INCI NAME Amount (%) Base Silicone Acrylate (50% Active 20 Phase inIsododecane) Silicone Dimethiconol 7.5 Phase Isododecane QS Total 100

What is claimed is:
 1. A cosmetic composition capable of forming amultilayer structure after application to a keratinous materialcomprising at least two immiscible components prior to application,wherein the at least two immiscible components are Component A andComponent B and Component A and Component B are separated in thecosmetic composition, wherein component A comprises about 0.01% to 60%by weight with respect to the total weight of the composition of atleast one silicone and/or hydrocarbon-containing film-forming agentselected from the group consisting of a film forming agent selected fromthe group consisting of silicone-containing film forming agents,polysaccharides, high viscosity esters, polybutenes, polyisobutenes,polyhydrogenated butenes, acrylic polymers, acrylate copolymers, vinylpyrrolidone containing homopolymers and copolymers, polyurethanes,polyolefins, and mixtures thereof; wherein component B comprises one ormore silicone compounds selected from the group consisting ofdimethicone, dimethiconol, cyclopentasiloxane, diisostearoyltrimethylolpropane siloxy silicate, diphenyl dimethicone, and mixturesthereof; and wherein, prior to application to keratinous material, thecosmetic composition is mixed such that Component A and Component B aretemporarily miscible upon application to keratinous material and, afterapplication to keratinous material, Component A separates from ComponentB to form a multilayer structure on keratinous material comprising LayerA corresponding to Component A and Layer B corresponding to Component B.2. The cosmetic composition according to claim 1: wherein that at leastone silicone and/or hydrocarbon-containing film-forming agent isselected from the group consisting of a film forming agent selected fromthe group consisting of silicone-containing film forming agents, acrylicpolymers, acrylate copolymers, vinyl pyrrolidone containing homopolymersand copolymers, polyurethanes, polyolefins, and mixtures thereof.
 3. Thecosmetic composition according to claim 1: wherein that at least onesilicone and/or hydrocarbon-containing film-forming agent is selectedfrom the group consisting of polyurethanes.
 4. The cosmetic compositionaccording to claim 1, further comprising at least one colorant.
 5. Thecosmetic composition according to claim 4, wherein the at least onecolorant is an inorganic pigment.
 6. The cosmetic composition accordingto claim 5, wherein the inorganic pigment is selected from the groupconsisting of iron oxide, titanium oxide, ultramarine blue, andcombinations thereof.
 7. The cosmetic composition according to claim 1,wherein the cosmetic composition is anhydrous.
 8. The cosmeticcomposition according to claim 2, wherein the one or more siliconecompounds selected from the group consisting of dimethicone,dimethiconol, diphenyl dimethicone, and mixtures thereof.
 9. Thecosmetic composition according to claim 2, wherein the one or moresilicone compounds is a diphenyl dimethicone.
 10. A kit comprising: (a)the cosmetic composition according to claim 1; (b) at least onecontainer which contains the cosmetic composition; and (c) at least oneapplicator.
 11. The kit of claim 10, wherein the container is configuredto mix Components A and B.
 12. A method of applying the cosmeticcomposition according to claim 1 to a keratinous material comprisingmixing the cosmetic composition to form a mixed composition in whichComponent A and Component B are temporarily miscible, and applying themixed composition to the keratinous material.
 13. The cosmeticcomposition according to claim 1, wherein the cosmetic composition doesnot contain fluorinated compound.
 14. The cosmetic composition accordingto claim 1, wherein the keratinous material is lip or skin.
 15. Thecosmetic composition according to claim 1, wherein the cosmeticcomposition is not an emulsion.
 16. The cosmetic composition accordingto claim 1, wherein the cosmetic composition does not containsurfactant.